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中国物理学会期刊

R(Fe,Mo)12型稀土永磁材料热膨胀反常现象研究

CSTR: 32037.14.aps.54.4240

Anomalous thermal expansion of R(Fe, Mo)12 compounds

CSTR: 32037.14.aps.54.4240
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  • 采用x射线粉末衍射方法测量了不同温度下R(Fe,Mo)12化合物(R=Nd,Y,D y)的晶格常数,对沿不同轴向的热膨胀反常程度进行了计算.分析认为R(Fe,Mo)12化合物热膨胀反常主要取决于Fe-Fe相互作用,根据Nd(Fe,Mo)12的结构参 数,不仅较短的Fe-Fe键负相互作用对热膨胀反常有贡献,8j-8j等较强的Fe-Fe正相互作用 也有很大贡献.另外还讨论了第三元素Mo的替代作用影响热膨胀反常的机理.

     

    The R(Fe, Mo)12 (R=Nd, Y, Dy) samples have been prepared and measure d by x-ray diffraction at different temperatures. The crystal lattice constant s and degree of the thermal expansion along the different axes are calculated. As a result, we consider that the abnormally thermal expansion of R(Fe, Mo)12 compounds is mainly determined by the Fe-Fe interaction. According to structural parameters of Nd(Fe, Mo)12, the anomaly is caused not on ly by the short Fe-Fe interaction as the previous explanation on other R-Fe inte rmetallic compounds but also by the other strongly positive Fe-Fe interactions. The mechanism of the substitution by Mo affecting the thermal expansion anomal ies is also discussed.

     

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