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中国物理学会期刊

LaCoO3中自旋态转变现象的超声研究

CSTR: 32037.14.aps.54.4379

Ultrasonic studies of the spin-state transition and the local distortion in LaCoO3

CSTR: 32037.14.aps.54.4379
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  • 测量了LaCoO3单相多晶样品的纵波与横波超声声速和衰减随温度的变化关系, 在材料的自 旋态转变温度附近(≈90K),纵波声速出现明显的软化并伴随一个尖锐的衰减峰,但是在 横波的测量中却没有出现类似的超声异常,分析认为LaCoO3在90K附近的自旋态 转变是由于Co3+离子是从低自旋态(LS,t62ge0 g)转变到中等自旋态(IS,t5 2ge1g ),而不是高等自旋态(HS,t42ge2g).随着温度的升高,在 200K附近纵波和横波测量上都观察到一个伴随着微小声速软化的宽大的衰减峰,这可能是随 机分布的IS态Co3+离子的Jahn-Teller效应导致的局域晶格扭曲所造成的.

     

    Temperature dependence of longitudinal and transverse ultrasonic velocities and attenuations of the single-phase polycrystalline LaCoO3 were presente d. A clear softening in the longitudinal ultrasonic velocity accompanied by a sharp peak in attenuation were observed near the spin-state transition temperature(≈90K), which did not appear in the transverse mode measurement. This anomalous ultraso nic behavior further demonstrates that the spin-state transition of Co3+ ions in LaCoO3 near 90K are more likely from a low spin state (LS,t62ge 0g) to an intermediate spin state (IS,t5 2ge1g ) than to a high s pin state (HS,t42ge2g ). A b ig attenuation peak accompanied by a slight softening in velocity was observed near 200K in both longitudinal and tr ansverse modes, which was probably caused by the relaxation of the local distort ions originating from Jahn-Teller effect of the randomly distributed IS state Co 3+ ions.

     

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