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中国物理学会期刊

碱金属和碱土金属氟化物对掺Er3+氟磷酸盐玻璃光谱性质的影响

CSTR: 32037.14.aps.54.4926

Spectroscopic properties of Er3+-doped alkaline/alkaline-earth metal modified fluorophosphate glasses

CSTR: 32037.14.aps.54.4926
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  • 研究了碱金属和碱土金属离子修饰的掺Er3+氟磷酸盐玻璃的光谱性质,讨论 了碱金属和碱土金属对铒氟磷玻璃的吸收和发射截面、荧光半高宽,Judd-Ofelt强度参数和 上转换发光强度等光谱性质的影响,并与一些传统氧化物玻璃系统进行了比较.研究表明碱 金属K+和碱土金属Sr2+掺杂高的玻璃更适宜用作光放大器基质. 含12mol%K+的氟磷玻璃展现出7.83×10-21cm2的高 发射截面和最小的荧光上转换强度;含23mol%Sr2+的氟磷玻璃则有7.58×10 -21cm2的高发射截面、65nm的荧光半高宽及8.6ms的长的上能级荧 光寿命.

     

    This paper reports the spectroscopic properties of Er3+-doped Al(PO 3)3-based fluorophosphate glasses for 1.5μm optical ampl ifiers. Effects of alkaline/alkaline-earth metal composition on the spectroscopi c properties of Er3+ in fluorophosphate glasses are investigated. A strong correlation between the alkaline/alkaline-earth metal content and the s pectroscopic parameters, such as absorption and emission cross sections, Judd-Of elt intensity parameters and upconversion emission intensity, has been observed. The fluorophosphate glass with 12 mol% potassium fluoride exhibits the largest calculated stimulated-emission cross-section of 7.83×10-21cm2 and the smallest upconversion emission intensity among the fluorophosphate studied. The fluorophosphate glass with 23 mol% strontium fluoride has a broadb and near-infrared emission at 1.5μm with a full width at half-maximum over 65nm and a long upper level fluorescence lifetime of 8.6ms.

     

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