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中国物理学会期刊

掺铒氟(卤)磷碲酸盐玻璃的上转换发光性能研究

CSTR: 32037.14.aps.55.1486

Upconversion emission properties of Er3+ in fluoride (halide) phosphate tellurite glasses

CSTR: 32037.14.aps.55.1486
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  • 研究了掺铒氟(卤)磷碲酸盐玻璃的吸收光谱和上转换荧光光谱,探讨了Er3+在 氟(卤)磷碲酸盐玻璃中的上转换发光机理.在975nm激光二极管抽运下产生强烈的上转换红光 及绿光,且红光的发光强度要远远大于绿光.以PbCl2取代PbF2后, 红光的发光强度下降,而绿光却没有明显变化;以ZnCl2取代ZnF2 达5mol%时,红光和绿光的发光强度均明显增大.

     

    The absorption and upconversion spectra of Er3+-doped fluoride (halid e) phosphate tellurite glasses were investigated for the first time, and the upc onversion mechanisms were studied. Strong red and green upconversion luminescenc e were observed under 975nm laser diode excitation at room temperature. When PbF 2 is partially replaced by PbCl2 gradually, the intensity of red emission decreases, while the green emission intensity changes only sligh tly. When ZnF2 is replaced by 5mol% ZnCl2, both red and gr een emissions intensity are enhanced obviously.

     

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