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中国物理学会期刊

过渡金属Fe,Co,Ni居里点附近热电势的实验研究

CSTR: 32037.14.aps.55.2529

Experimental study on thermopower of transition metals Fe,Co and Ni in the vicinity of Curie temperatures

CSTR: 32037.14.aps.55.2529
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  • 测量了纯金属Fe,Co,Ni的热电势发现,在居里点附近热电势随温度的变化关系曲线均呈现先凹后凸的反常现象.由曲线的转折处可确定三个居里温度,即铁磁态居里点Tf,居里点TC和顺磁居里点θp.由曲线可见,金属由铁磁态到顺磁态的相转变,存在一定温度间隔的转变过程,居里温度是这一过程的中间温度.分析曲线表明,温度在Tf与TC范围有空穴参与导电,说明磁性负载者是d带中的空穴.对于温度在TC与θp范围可能存在短程有序进行了讨论.

     

    Thermopower of pure metals of Fe ,Co and Ni were measured in the vicinity of Curie temperatures.The results show that the curves of thermopower against temperature behave very similarly, being concave first and convex subsequently. Consequently, three special points for each metal can be determined by the corresponding curve, namely the ferromagnetic Curie temperature Tf, Curie temperature TC, and paramagnetic Curie temperature θp. It is obvious that there is a definite transition interval of temperature between ferromagnetic state and paramagnetic state of the metal and the Curie temperature is only an intermediate value. A discussion is made which concludes that the holes in the d band contribute to the electrical conduction in the temperature interval between Tf and TC, which implies that the magnetic carriers are the holes. It is also contemplated that there may exist short range order between TC and θp.

     

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