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中国物理学会期刊

Tb0.3Dy0.7(Fe0.9T0.1)1.95合金的结构、自旋重取向和穆斯堡尔谱

CSTR: 32037.14.aps.55.879

Structure, spin reorientation and M?ssbauer spectra of Tb0.3Dy0.7(Fe0.9T0.1)1.95 alloys

CSTR: 32037.14.aps.55.879
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  • 系统研究了室温下Tb0.3Dy0.7(Fe0.9T0.1)1.95(过渡金属元素T=Mn,Fe,Co,B,Al,Ga)合金中ⅢA族金属和过渡金属元素T替代Fe对结构、自旋重取向和穆斯堡尔谱的影响.结果发现,不同金属T替代Fe,Tb0.3Dy0.7(Fe0.9T0.1)1.95,合金具有相同的MgCu2型立方Laves相结构;Al,Ga替代使Tb0.3Dy0.7(Fe0.9T0.1)1.95合金的易磁化方向在110面逐渐偏离了立方晶体的主对称轴,即自旋重取向,B,Mn,Co替代未使易磁化轴发生明显转动;Al,Ga元素替代使超精细场Hhf略有下降,B,Mn替代对超精细场Hhf的影响不大,而Co元素替代使超精细场Hhf有较大增加;所有元素替代使同质异能移IS有所增加;B,Al,Ga和Mn替代使四极劈裂Qs增加,而Co替代使四极劈裂Qs下降.

     

    The effect of T substitution for Fe on the structure, spin reorientation and Mssbauer spectra of a series of Tb0.3Dy0.7(Fe0.9T0.1)1.95 (T=Mn,Fe,Co,B,Al,Ga) alloys at room temperature has been investigated systemically. The X-ray result shows that all samples are single phase having the cubic Laves-phase structure (C15). The analysis of the Mssbauer spectra indicates that the easy magnetization direction in the 110 plane deviates slightly from the main axis of symmetry for Al and Ga substitution, but remains in the [111] direction for B, Mn and Co substitution. The hyperfine field decreases slightly for Al and Ga substitution, does not change for B,Mn substitution and increases greatly for Co substitution. With the substitution of all elements but Co, the isomer shift and the quaduple splitting always increase.

     

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