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中国物理学会期刊

制备工艺对p型碲化铋基合金热电性能的影响

CSTR: 32037.14.aps.56.2858

Effect of preparation methods on thermoelectric properties of p-type Bi2Te3-based materials

CSTR: 32037.14.aps.56.2858
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  • 利用区熔法、机械合金化、放电等离子烧结(SPS)技术、热压法等多种工艺制备了p型碲化铋基热电材料.在300—500K的温度范围内测量了各热电性能参数,包括电导率(σ)、塞贝克系数(α)和热导率(κ),研究了制备工艺对热电性能的影响.结果表明,所制备的块体材料与同组成区熔晶体相比,性能优值ZT均有不同程度的提高.其中,利用区熔法结合SPS技术可获得热电性能最佳的块体材料,其ZT值达1.15.

     

    p-type Bi2Te3-based thermoelectric materials were fabricated by various methods, such as zone-melting, mechanical alloying, spark plasma sintering (SPS) and hot-pressing. Electrical conductivity (σ), Seebeck coefficient (α), and thermal conductivity (κ) were measured in the temperature range of 300—500K. The influence of the preparation methods on thermoelectric properties was studied. Compared with that of the zone-melted ingot, the figure of merit ZT (ZT=α2σT/κ) of those materials fabricated by the other methods mentioned were all increased to some extent. The obtained maximum ZT value was about 1.15 for that fabricated by the combination of zone-melting and spark plasma sintering technique.

     

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