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中国物理学会期刊

Tm3+掺杂硅酸镓镧(La3Ga5SiO14)晶体的结构与光学性能研究

CSTR: 32037.14.aps.56.2968

Structure and spectroscopic properties of Tm3+ doped langasite (La3Ga5SiO14) crystal

CSTR: 32037.14.aps.56.2968
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  • 利用X射线粉末衍射确定了Tm3+掺杂硅酸镓镧(La3Ga5SiO14,LGS)晶体的晶体结构;运用DICVOL91程序计算了该晶体不同部位的晶胞参数;测定了Tm:LGS晶体的室温吸收谱和470nm光激发下的发射光谱;根据Judd-Ofelt理论拟合了Tm3+的三个晶场调节参数Ωt(t=2,4,6),分别为2.694×10-20cm2,1.842×10-20cm2,0.030×10-20cm2;计算了各个能级跃迁的谱线强度、振子强度、吸收截面等,进而计算了3H4和3F4态的自发跃迁概率、辐射寿命、荧光分支比和积分发射截面,并对结果进行了分析.

     

    The structure of Tm3+-doped langasite(La3Ga5SiO14,abbreviated as LGS) crystal has been measured by XRD. The crystal lattice parameters were calculated with DICVOL91 program. The absorption spectra and emission spectra (excitated under 470nm) of Tm:LGS single crystal was measured at room temperature. And the optical parameters, such as transition-line intensity, oscillator strength and absorption section were calculated by using Judd-Ofelt theory. The three intensity parameters Ωt(t=2,4,6) were fitted to be 2.694×10-20cm2,1.842×10-20cm2,0.030×10-20cm2,respectively. The lifetime, branching ratio and integrated stimulated-emission cross section were obtained and the results were discussed.

     

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