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中国物理学会期刊

原位氧化Zn3N2制备p型ZnO薄膜的性能研究

CSTR: 32037.14.aps.56.4914

Preparation of p-type ZnO thin films by in situ oxidation of Zn3N2

CSTR: 32037.14.aps.56.4914
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  • 采用射频反应溅射法在玻璃衬底上制备Zn3N2薄膜,然后向真空室中通入纯氧气进行热氧化制备ZnO薄膜.利用X射线衍射、扫描电子显微镜、霍尔效应测量、透射光谱和光致发光光谱等表征技术,研究了氧化温度和氧化时间对ZnO薄膜的结晶质量、电学性质和光学性能的影响.研究结果显示,450 ℃ 下氧化2 h后的样品中除含有ZnO外,还有Zn3N2成分,500 ℃下氧化2 h可以制备出电阻率为0.7 Ωcm,空穴载流子浓度为10 

    Low resistance p-type ZnO thin films were prepared by in situ oxidation of Zn3N2 films which were deposited by reactive radio-frequency magnetron sputtering of zinc in Ar-N2 mixture atmosphere. The effects of oxidation temperature and time on structural, electronic and optical properties of the samples were investigated by X-ray diffraction, scanning electron microscopy, Hall-effect measurements, transmittance spectra and photoluminescence spectra. It was found that the sample oxidized at 450 ℃ contains Zn2N3 besides ZnO. The sample oxidized at 500 ℃ for 2 h had good properties of low resistance (0.7 Ωcm), good transmittance rate (above 85%),predominant excitonic ultraviolet emission with narrow full width at half maximum and weak deep level visible emission. The low resistance p-type ZnO films could be used in short wavelength industrial application.

     

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