The extraterrestrial spectrum in the visible wavelength range of 340.5—818.6nm at the height of 9.6 km has been detected，furthermore，the upper sunlightand skylight spectra have been collected in different regions of Chengdu and Lijiang. The date and diagram indicated that 482.1nm is the hightest point in extraterrestrial direct solar spectra, and that of the extraterrestrial skylight spectra is shifted to 412nm. The skylight spectra registered on sunny and cloudy days are notably different. It was also found that the firn on top the Yulong Mountain has different albedos in different wavebands visible range.