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中国物理学会期刊

金属/掺杂聚合物/金属结构中载流子的注入与输运

CSTR: 32037.14.aps.57.1117

Injection and transport of the charge carriers in metal/impurity polymer/metal structure

CSTR: 32037.14.aps.57.1117
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  • 基于紧束缚的Su-Schrieffer-Heeger模型,利用非绝热的动力学方法,研究了金属/聚合物/金属三明治结构中载流子注入与输运的动力学过程,其中,聚合物中含有一个掺杂离子. 电子波函数随时间的演化满足含时Schrdinger方程,晶格运动满足经典的牛顿运动方程. 研究发现,掺杂离子对注入到聚合物中的载流子的作用类似一个控制阀门,阀门的状态与电场的强度和偏压的大小密切相关.

     

    Using the tight-binding Su-Schrieffer-Heeger (SSH) model and a nonadiabatic dynamical evolution method, the dynamic process of the charge carrier injection and transport through metal/ polymer/metal structure was studied, for which the polymer chain contains an impurity ion. The electron wave function was described by the time-dependent Schrdinger equation, while the polymer lattice was treated classically by the Newtonian equations of motion. It was found that the impurity ion acts as a control gate on the charge carriers, while the state of the control gate is determined by the strength of the electric field and the magnitude of the bias voltage.

     

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