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以Nd:YAG激光器的二倍频输出光为抽运光，其三倍频输出抽运的光学参量发生/放大器输出光为探测光，利用光学-光学双色双共振多光子离化光谱技术(OODR-MPI),获得了NO2分子在605—675nm探测光波长范围内的多光子离化激发谱. 通过对NO2分子离化机理的分析，确定了在此波长区间，NO2分子经1+3+1双共振多光子过程离化，离化通道为NO2(X2A1)hν
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关键词:
- NO2 /
- 光学-光学双共振多光子离化谱 /
- 里德伯态 /
- 分子常数
The optical-optical double resonance multiphoton ionization (OODR-MPI) technique has been applied to the study of the Rydberg states of nitrogen dioxide. The results show that NO2 molecule is ionized though a 1+3+1 double resonance multiphoton ionization process in 605—675nm probe wavelength region. The ionization pathway is: NO2(X2A1)hν1NO2(A2B2)3hν2NO2(3pσu)hν2NO22+e. The OODR-MPI spectrum corresponds to the excitation of NO2 3pσu Rydberg state by a three photon process. The value ω1=(1422.5±23.5) cm-1 and ω2＝(590.5±4.9) cm-1 of symmetric stretching and bending vibration frequencies of this Rydberg state are presented. The position of the band origin and the quantum defect of 3pσu Rydberg state are obtained to be (58331±71) cm-1 and 0.69, respectively.-
Keywords:
- NO2 /
- OODR-MPI spectrum /
- Rydberg state /
- molecular constant
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中国物理学会期刊
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