搜索

x
中国物理学会期刊

Cd掺杂p型Ge基Ba8Ga16CdxGe30-x Ⅰ型笼合物的结构及热电特性

CSTR: 32037.14.aps.58.4274

Structure and thermoelectric properties of p-type Ge-based Ba8Ga16CdxGe30-x type-Ⅰ clathrates doping by Cd

CSTR: 32037.14.aps.58.4274
PDF
导出引用
  • 以Cd作为掺杂元素,用熔融法结合放电等离子体烧结(SPS)技术制备了具有不同Cd含量的Ba8Ga16CdxGe30-x(x=0.95, 1.00, 1.05, 1.10) Ⅰ型笼合物,研究了Cd掺杂对其结构及热电性能的影响.Rietveld结构解析表明所制备的Ba8Ga16CdxGe30-

     

    Cd-doping Ba8Ga16CdxGe30-x(x=0.95, 1.00, 1.05, 1.10) type-I clathrates with different Cd contents were synthesized by combining solid-state reaction with spark plasma sintering (SPS) method. The effects of Cd doping on the structure and thermoelectric properties were investigated. Rietveld refinement reveals that Ba8Ga16CdxGe30-x compounds prepared by this method are type-I clathrates with space group pm3n; Cd atoms mainly occupy the 6c and 16i sites in the framework, and the atom displacement parameter (ADP) of Cd is relatively higher than that of other atoms. All specimens show the characteristics of p-type conduction. The carrier scattering mechanism is mainly ionized impurity mechanism in the low temperature range, and gradually changes to acoustical mechanism with the increase of temperature. With the increase of Cd content, the electrical conductivity increases while the Seebeck coefficient decreases gradually. The lattice thermal conductivity of the Ba8Ga16CdxGe30-x compounds is relatively low due to the larger ADP of Cd, and it decreases by about 38% compared with that of Ba8Ga16Ge30 The maximum ZT value of 0.173 is obtained at 600 K for Ba8Ga16Cd100Ge2900 compound.

     

    目录

    /

    返回文章
    返回