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中国物理学会期刊

B位等价掺杂SrBi4Ti4O15铁电材料的性能研究

CSTR: 32037.14.aps.58.7235

Effect of B-site equal-valent doping on ferroelectric properties of SrBi4Ti4O15 ceramics

CSTR: 32037.14.aps.58.7235
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  • 采用了传统的固相烧结工艺,制备了不同Zr和Hf掺杂量的SrBi4Ti4-xZrxO15(x=000,003, 006,010,020)和SrBi4Ti4-xHfxO15(x=000,0005, 0015,0030,0060)的陶瓷

     

    The structures and properties of Zr and Hf-modified SrBi4Ti4O15(SBTi) ceramics were investigated. We find that the basic crystal structure is not changed after the substitution of equal-valent cations Zr4+ and Hf4+ for the Ti4+ ions at B site in SBTi. Compared with the higher-valent cation doping (V, Nb), Zr4+ and Hf 4+ substitution can also improve the ferroelectric property of SBTi. The enhancement of remnant polarization (2Pr) by Hf4+ doping is obviously larger than that by Zr4+ doping, though these two cations have almost the same radius. This indicates that the reduced concentration of oxygen vacancy is not the only reason responsible for the improvement of the 2Pr in the B site doping, and other uncertain reasons should also be considered. The piezoelectric properties of these ceramics are investigated briefly. The tendency of piezoelectric constant changing with the doping dosage is nearly consistent with the tendency of 2Pr. Meanwhile, the dielectric properties of these ceramics are investigated, the Curie temperature of the samples varieds slightly with the doping amount, which implies that the good thermal stability of SBTi is not sacrificed.

     

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