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中国物理学会期刊

高折射率Nd,La共掺杂氧化钇透明陶瓷的光谱性质及其Judd-Ofelt理论分析

CSTR: 32037.14.aps.59.300

Spectroscopic properties and Judd-Ofelt theory analysis of La, Nd codoped Y2O3 high refractivity transparent ceramics

CSTR: 32037.14.aps.59.300
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  • 采用液相法和真空烧结技术制备了20%Nd,30%La共掺杂Y2O3透明陶瓷样品.样品晶粒均匀,大小在22 μm左右,在晶粒和晶界处都未见气孔.元素线扫描结果表明,Nd离子和La离子均匀地分布于陶瓷晶粒和晶界处.并测试了样品的吸收光谱和荧光光谱.样品在主吸收峰821 nm处的吸收截面为43×10-24 m2,主荧光发射峰位于1078 nm处,实测荧光寿命为0287 ms.采用Judd-Ofelt理论计算了Nd 

    Nd,La:Y2O3 nanocrystalline powder was prepared by co-precipitation method. The transparent ceramic was fabricated by vacuum sintering at 1700℃ for 4 h in vacuum. Transparent polycrystalline ceramics with uniform lanthanum distribution was obtained. The grain size was around 22 μm. No pores were found in the grain and grain boundary. The absorption spectrum and the fluorescence spectrum of the sample were measured. The highest absorption peak is centered at 821 nm and the absorption cross section is 43×10-24 m2 The main emission peak is at 1078 nm, and the fluorescence lifetime is 0287 ms. The Judd-Ofelt intensity parameter Ωλ(λ=2,4,6), spontaneous transition probability, radiative lifetime and fluorescence branching ratio of Nd3+ were calculated by Judd-Ofelt theory. The calculated emission cross section of 4F3/2→4I11/2 transition is 20×10-24 m2 It was found that the addition of La ion can change the crystalline field of yttria, which helps to obtain suitable solid laser materials.

     

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