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中国物理学会期刊

二维链间扩展的极化子动力学研究

CSTR: 32037.14.aps.59.6405

Dynamics of two-dimensional interchain delocalized polarons

CSTR: 32037.14.aps.59.6405
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  • 基于扩展的SSH模型,研究了有序耦合聚合物链系统中的极化子动力学,包括极化子的形成过程及其在外场下的输运.发现,当聚合物链间的耦合较强时,注入到系统中的电子会诱发二维链间扩展的极化子态,分布在多条聚合物链上.另外,动力学模拟表明,与一维链内定域极化子相比,在相同的电场强度下二维极化子具有更大的运动速度,这与实验结果一致.

     

    Based on the SSH model, polaron dynamics in a system of highly ordered conjugated polymer chains is investigated, including polaron formation and transport in the presence of an external electric field. It is found that, beyond a certain strength of the interchain coupling, the injected electron will induce a two-dimensional delocalized polaron state, expanding over several chains. Dynamical simulations suggest that, under the same electric field, two-dimensional interchain delocalized polarons move faster than intrachain localized polarons, as suggested by earlier experiments.

     

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