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中国物理学会期刊

Er0.3Gd0.7VO4晶体红外量子剪裁效应及其在太阳能电池应用上的研究

CSTR: 32037.14.aps.59.8191

Infrared quantum-cutting analysis of Er0.3Gd0.7VO4 crystal for solar cell application

CSTR: 32037.14.aps.59.8191
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  • 研究了高浓度的Er0.3Gd0.7VO4晶体材料的红外量子剪裁现象,结果发现光激发2H11/2能级和4G11/2能级的4I13/2→4I15/2荧光跃迁的近似的量子剪裁效率η’已达约178.55%和177.61%

     

    Recently the infrared quantum cutting has achieved an exciting development in enhancing the efficiency of solar cell. The infrared quantum cutting of Er0.3Gd0.7VO4 crystalline is studied in the present paper. It is found that the approximate quantum cutting efficiencies of 1532.5 nm 4I13/2→4I15/2 fluorescence, when the 2H11/2 and 4G11/2 levels are excited, are about 178.55% and 177.61% respectively. Especially, effective three-photon and four-photon infrared quantum cuttings of Er0.3Gd0.7VO4 crystalline excited by visible and near-violet light are found for the first time in the present paper. An interesting "peak - valley" conversion phenomenon in the excitation spectrum is also observed. It is also the first time for us to find the first-order infrared quantum cutting based single species Er3+ ion for Er0.3Gd0.7VO4 crystalline.

     

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