A novel optical high-density storage material ADPA-PVK-PBA-TNF polymer film was reported. In the nonresonant absorption of sample, we tested and investigated its photo-induced birefringence and obtained the value Δn =1.3×10-3.We analyzed the physico-chemiscal mechanism of orientation-enhancement and discussed the enhancing/restraining effects of photo-induced birefringence in the film. On this basis,multiple angles storage were achieved and clear holographic storage images were gained. The enhancing/restraining effect of image storage was also discussed. And with the help of this effect one can process and remove storage images.