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中国物理学会期刊

辐照对掺Er硅酸盐玻璃吸收和发光特性的影响

CSTR: 32037.14.aps.61.116301

Gamma radiation effects on absorption and emission properties of erbium-doped silicate glasses

CSTR: 32037.14.aps.61.116301
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  • 用传统的高温熔融法熔制了一系列掺Er硅酸盐玻璃, 并测试了这些样品经5 kGy 射线辐照前后紫外至近红外的吸收和荧光光谱. 实验结果表明, 辐致暗化效应使得玻璃材料中形成了大量色心, 导致在400 nm附近出现强吸收带, 其尾端延伸至近红外区. 辐照产生的新能带增加了基质与Er3+ 特定能级(如2H11/2, 4S3/2及4F9/2等) 之间的能量传递, 从而使辐照后的样品荧光寿命减小, 且在相同激发条件下荧光强度下降. 室温下辐照样品在荧光测试过程中出现了漂白现象.

     

    A series of Er-doped silicate glasses is prepared by a conventional melting method under normal processing conditions, and the effects of gamma-ray radiation on absorption and emission properties of all samples are investigated. The radiation-induced darkening causes a strong broad optical absorption band that has a maximum around 400 nm and extends to the near infrared region. The point defects generated in the silicate matrix by irradiation around the Er3+ ion favor the activation of non-radiative relaxation channels thus modifying the photoluminescence quantum efficiency from specific excited levels, such as those emitting at 520 and 650 nm. Photobleaching effects are observed in Er-doped silicate glasses pumped by 980 nm LD at room temperature.

     

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