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中国物理学会期刊

分子极性对类胡萝卜素共振拉曼光谱的影响

CSTR: 32037.14.aps.62.037801

Effect of molecule polarity on the resonance raman spectrum of caroteniod

CSTR: 32037.14.aps.62.037801
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  • 测量了非极性分子胡萝卜素和极性分子角黄素, 在非极性溶剂CS2和极性溶 剂1,2二氯乙烷中243293 K的温度范围内的共振拉曼光谱. 结果表明, 溶质和溶剂的极性对拉曼光谱影响很大. 非极性分子胡萝卜素在非极性溶剂CS2中的拉曼散射截面最大, 线宽最窄, 而极性分子角黄素在极性溶剂1,2二氯乙烷中的拉曼散射截面最小, 线宽最大. 用溶剂效应及线性多烯分子的相干弱阻尼电子-晶格振动, 有效共轭长度模型给予了解释.

     

    The resonance Raman spectra of nonpolar molecule all-trans--carotene and polar molecule canthaxanthin in nonpolar CS2 and polar 1,2-dicholoroethane in a temperature range from 243K to 293K are measured. The results show that polarities of the solute and solvent have a great effect on Raman spectrum. Raman scattering cross-section of nonpolar all-trans--carotene in nonpolar solvent CS2 is biggest and its bandwidth is narrowest. Raman scattering cross-section of polar canthaxanthin in polar solvent 1,2-dicholoroethane is smallest and its bandwidth is widest. The experimental phenomena are explained by solvent effects, coherent weakly damped electron-lattice vibration and effective conjugated length.

     

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