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中国物理学会期刊

基于一维光子晶体的新型背反射器及其在非晶硅薄膜太阳电池中的应用

CSTR: 32037.14.aps.63.077301

One-dimensional photonic crystal(1D PC)-based back reflectors for amorphous silicon thin film solar cell

CSTR: 32037.14.aps.63.077301
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  • 本文研究制备一种由低折射率的SiOx层与高折射率的a-Si层周期性交叠构成的新型一维光子晶体(1D PC)背反射器. 研究结果表明,随着SiOx/a-Si交叠周期数的增加,一维光子晶体的反射率逐步提高. 当周期数大于3时,在空气中500–750 nm波长范围的平均反射率达到96%. 将该一维光子晶体作为背反射器应用于NIP型非晶硅电池(电池结构为玻璃/1D PC/AZO/NIP a-Si:H/ITO),当光子晶体周期为4时,效率达到7.9%,略优于传统的AZO/Ag背反射电极结构电池(7.7%),明显高于不锈钢衬底电池(6.9%),相对效率提升14.5%.

     

    New-type back reflectors based on one-dimensional photonic crystal (1D PC) for amorphous silicon thin film solar cells have been investigated, designed and fabricated. These 1D PCs consist of alternating amorphous Si (a-Si) and silicon dioxide (SiOx), of which the deposition process is compatible with current silicon thin film solar cells technology. Results indicate that the total reflectance of 1D PCs increases with the increase of period number. An average reflectance over 96% can be achieved in the range from 500 to 750 nm with 4 periods or more. Applying the 4-period 1D PC as back reflector in NIP amorphous silicon thin film solar cell with device-configuration of glass/1D PC/AZO/NIP a-Si:H/ITO, a conversion efficiency of 7.9% can be obtained, which is comparable to the AZO/Ag-based solar cell of 7.7% and is much better than the SS-based solar cell of 6.9% (a relative enhancement of 14.5%).

     

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