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中国物理学会期刊

基于傅里叶变换的波长扫描腔衰荡光谱

CSTR: 32037.14.aps.68.20191062

Wavelength-scanned cavity ring down spectroscopy based on Fourier transform

CSTR: 32037.14.aps.68.20191062
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  • 连续波腔衰荡光谱(CW-CRDS)采用腔长扫描方式, 光谱间隔可任意长, 适合弱吸收条件下气体参数或谱线参数的精确测量. CW-CRDS腔长扫描可使任意波长激光耦合进腔, 此时激光波长波动会降低光谱的信噪比. 为此, 本文提出了一种基于傅里叶变换的、快速波长扫描的CRDS方法(FTS-CRDS), 该方法在高速扫腔的同时连续扫描激光波长, 得到周期性的蕴含气体吸收信息的衰荡时间, 然后对其进行傅里叶变换, 提取其特征频率以精确复现气体吸收光谱. FTS-CRDS能有效消除激光波长波动等导致的光谱噪声, 提升复杂线型中谱线参数的测量精度, 且无需采用波长计实时测量激光绝对波长, 可使测量系统更紧凑、经济. 实验采用低压下CO分子的6371.299 cm–1和6374.406 cm–1谱线对该方法进行了验证, 相比CW-CRDS, 该方法有效消除了激光波长波动导致的谱线两翼处噪声, 光谱信噪比提高了4倍以上; 测得的谱线参数与CW-CRDS一致, 但具有更小的测量不确定度.

     

    Continuous wave cavity ring down spectroscopy (CW-CRDS) method with using cavity length scanning is ideal for accurately characterizing the low pressure spectra and measuring the small spectral parameters (such as the Dicke narrowing coefficient and the speed dependent collision broadening coefficient). However, the laser of any wavelength can be coupled to the cavity due to the cavity scan, so the spectral noise caused by the laser wavelength fluctuations cannot be ignored. This noise is non-uniformly distributed in the spectrum (especially on both wings on the spectral line) and is difficult to eliminate even with long-term averaging. Unlike the complex laser frequency locking techniques or the optical frequency combs or the better lasers, in this paper, a simple, easy to operate, fast wavelength-scanned CRDS method is proposed based on Fourier transform. The laser wavelength is continuously tuned across the absorption line to measure the periodic ring-down time. A reconstruction algorithm is developed to precisely recover the absorbance by extracting the characteristic frequencies of the periodic ring-down time after the Fourier transform. An etalon, instead of the wavelength meter, is used to calibrate the relative laser wavelength. This method effectively eliminates the non-uniform spectral noise caused by laser wavelength fluctuation in traditional CW-CRDS and significantly improves the measurement accuracy of spectral line parameters (especially line parameters in complex line shapes, such as speed dependent Voigt line shape) at low pressure. In addition, the measuring system, in which no wavelength meter is used, is simpler, more economical than CW-CRDS. The smaller residuals of the Galatry profile fit to the measured CO transitions at R(5) 6371.299 cm–1 and R(6) 6374.406 cm–1 show that the noise on both wings of the spectra, caused by laser wavelength fluctuation, is effectively reduced and the spectral SNR is then improved. The measured N2 perturbed collision broadening coefficient of the Voigt profile fit for CO is consistent with that from the classical CW-CRDS method and is in good agreement with the HITRAN2016 database. The measured N2 perturbed Dicke narrowing coefficient of the Rautian and Galatry profile and speed dependent collision broadening coefficient of the speed dependent Voigt profile have very good linear relationship with pressure, and have smaller uncertainties than the results from the CW-CRDS method.

     

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