搜索

x
中国物理学会期刊

固态锂电池中的机械力学失效及解决策略

CSTR: 32037.14.aps.69.20200713

Mechanical failures in solid-state lithium batteries and their solution

CSTR: 32037.14.aps.69.20200713
PDF
HTML
导出引用
  • 固态锂电池中电极材料与固态电解质的力学性能对于电池的机械稳定性有重要影响, 如果电池内部的应力超过材料的强度, 则会在固态电池内部发生不同规模、不同组分的机械力学失效, 从而严重恶化电池的电化学性能. 本文从提高固态电池机械稳定性的角度出发, 阐述了固态电池中各组分的力学性能对固态电池机械稳定性的影响, 并分析了影响材料力学性能的因素. 另外, 固态锂电池在电池充放电过程中出现的机械力学失效问题, 包括电极材料/电解质的破裂/断裂、电极与电解质的接触损失以及由于锂枝晶引发的电池短路等, 也在综述中被讨论. 最后, 总结了目前解决固态锂电池中机械力学失效的一些常用策略, 并对未来该领域的研究方向进行了展望. 本文讨论的固态锂电池中的机械力学失效以及解决策略将有助于研究人员构筑高能量密度、长寿命、更安全的固态锂电池.

     

    The mechanical properties of electrode materials and solid-state electrolytes in solid-state batteries (SSBs) have an important influence on the mechanical stabilties of SSBs. Mechanical failures in SSBs on different scales and in different components will occur once the stress inside SSBs exceeds the materials’ strengths, which seriously deteriorates the electrochemical performances of SSBs. From the perspective of stabilizing the mechanical stabilities of SSBs, in this review we describe the influences of the mechanical properties of each component in SSBs on the mechanical stabilites of SSBs, and we analyze the factors that affect the mechanical properties of materials. In addition, we also discuss the mechanical failures of SSBs during cycle, including electrode materials’ or solid-state electrolytes’ fractures, electrode-electrolyte contact losses, and short-circuits due to lithium dendrites. Finally, we summarize some common strategies to mitigate the mechanical failures in SSBs, and look forward to the future research directions in this field. Overall, the mechanical failures in SSBs and their strategies discussed in this review will help researchers build SSBs with higher energy density, longer life and higher safety.

     

    目录

    /

    返回文章
    返回