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中国物理学会期刊

钙钛矿发光二极管光提取性能增强的研究进展

CSTR: 32037.14.aps.69.20200755

Research progress of enhancing perovskite light emitting diodes with light extraction

CSTR: 32037.14.aps.69.20200755
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  • 钙钛矿发光二极管具有色纯度高, 发光层材料带隙可调等优点, 目前其外量子效率已经超过20%, 在平板显示和照明领域有很好的商业化前景. 然而, 同有机发光二极管类似, 钙钛矿发光二极管同样存在衬底模式、表面等离子体模式、波导模式引起的内部损耗问题, 在一定程度上限制了钙钛矿发光二极管的性能提升. 因此, 需要优化器件的材料和几何结构以获得更好的膜间光学导纳匹配, 改善钙钛矿发光二极管光提取效率以增强器件的发光性能. 当前, 通过改变电极材料、增加等离子体激元、引入微纳结构以及优化钙钛矿薄膜和器件结构, 可以增强钙钛矿发光二极管光提取效率, 通过增强光提取效率后的钙钛矿发光二极管外量子效率可达 28.2%, 电流效率可达88.7 cd/A. 本文针对钙钛矿发光二极管材料与结构的改变, 从以上四个方面进行重点阐述. 此外, 进一步分析了这四种方法在提升器件光提取效率方面存在的优点和面临的问题, 从而为钙钛矿发光二极管的制备和优化提供一定的借鉴.

     

    Perovskite light emitting diodes (PeLEDs) have developed rapidly in recent years due to their advantages of tenability of band gap and high color purity. At present, the external quantum efficiency of PeLED has rised up to 20%. Like the scenario of organic light emitting diode, there exist various internal losses in PeLED with low light extraction efficiency. It arises from the absorption of substrates, waveguide transmission and surface plasmon resonance of metal electrode. To improve the luminescence performance of PeLED, a well-matched optical admittance between the thin-films inside the devices is required. In this paper, the strategies of enhancing the light extraction efficiency are adopted as the materials and structures in PeLED are concerned. The applications of alternative electrode in PeLED are discussed, such as graphene, silver nanowires, metal transparent electrode and some new-types of electrodes. In addition, the plasma effect is also introduced into the PeLED to deflect the emitting light. What is more, the nano-structure grating is inserted into device to reduce the optical losses due to the large refractive index difference between the interfaces in device. Therefore, the external quantum efficiency of PeLED rises up to 28.2%, and the current efficiency can reach 88.7 cd/A.

     

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