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中国物理学会期刊

钙钛矿太阳电池中各功能层的光辐照稳定性研究进展

CSTR: 32037.14.aps.70.20201762

Research progress of light irradiation stability of functional layers in perovskite solar cells

CSTR: 32037.14.aps.70.20201762
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  • 钙钛矿太阳电池简单的制备工艺、低廉的成本和优异的性能使其有望替代已产业化的硅太阳电池, 革新现有能源供给结构, 然而, 钙钛矿太阳电池的稳定性差制约了其产业化进程, 本文分别介绍了光辐照下, 钙钛矿薄膜内部本征的离子迁移行为和由此产生的磁滞、荧光淬灭/增强和电池失效问题; 以及典型的TiO2/钙钛矿界面的紫外光不稳定、空穴传输层和金属电极不稳定问题. 作为依光器件深刻理解其光辐照稳定性对顺利解决电池各种环境稳定性问题至关重要.

     

    The low-cost, high-efficiency and easy fabrication of perovskite solar cells make them an ideal candidate for replacing industrialized silicon solar cells, and thus reforming the current energy supply structure. However, the industrialization of perovskite solar cells is now restricted due to its poor stability. In this article, the intrinsic ion migration behavior in the perovskite film under light irradiation is introduced, which is mainly responsible for hysteresis, fluorescence quenching/enhancement and the failure of solar cell. In addition, the typical ultraviolet light instability of TiO2/perovskite interface, and the light instability of hole transport layer and metal electrodes are also discussed subsequently. As a light-dependent device, improving its light radiation stability is essential for making it suitable to various environmental applications.

     

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