Water is one of the most important substances in the world. It is a crucial issue to study the dynamics of water molecules at interfaces or in the confined systems. In recent years, the emerging magnetic resonance technique based on nitrogen-vacancy (NV) center has allowed us to observe the nanoscale nuclear magnetic signal and temperature simultaneously. Here we succeed in measuring the nuclear magnetic resonance (NMR) signals of nanoscale solid and liquid water on diamond surface by NV center, and observing the solid-liquid phase transition of these nano-water by temperature control. This work demonstrates that the nano-NMR technique based on NV centers can probe the dynamics behavior of nanoscale materials effectively, providing a new way for studying the nanoscale confined systems.