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中国物理学会期刊

4296—4302 cm–1范围内氨气光谱线强与自展宽系数测量研究

CSTR: 32037.14.aps.71.20220504

Measurement research of line intensity and self-broadening coefficient for NH3 spectra in 4296–4302 cm–1

CSTR: 32037.14.aps.71.20220504
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  • 由于HITRAN数据库中NH3在4296—4302 cm–1范围的谱线参数主要源于理论计算, 与实际情况存在差异. 为了修正数据库中该范围内NH3的谱线参数, 本文利用可调谐二极管激光吸收光谱(TDLAS)技术和计量学理论, 测量2—10 Torr(1 Torr = 133.322 Pa)高纯NH3在4296—4302 cm–1范围内的吸收光谱, 综合考虑压强、温度、气池光程、波数、线型拟合等主要影响因素, 对NH3在该波段的主要吸收谱线的线强和自展宽系数进行了反演和不确定度计算. 测量得到的线强与同行最新测量结果偏差在20%以内, 自展宽系数与HITRAN2020数据库偏差在14%以内, 二者的不确定度范围分别为0.63%—2.7%和0.77%—5.4%, 均小于HITRAN数据库中的不确定度范围10%—20%, 测量的部分谱线光谱参数在HITRAN中没有记录, 本文获得的结果对于补充和修正HITRAN数据中4296—4302 cm–1范围NH3的谱线参数具有参考意义.

     

    Spectral parameters of NH3 in a range of 4296–4302 cm–1 in the HITRAN database are different from the actual situation as they are derived from theoretical calculations. In order to correct the spectral parameters of NH3 in this range in HITRAN, tunable diode laser absorption spectroscopy (TDLAS) technology and metrological theory are used to measure the absorption spectrum high-purity NH3 in the range of 4296–4302 cm–1 at 2–10 Torr. The line intensity and self-broadening coefficient of the main absorption line of NH3 in this band are retrieved and their uncertainty are calculated by comprehensively considering main factors including pressure, temperature, optical path of gas cell, wavenumber and line shape fitting. The discrepancies between our measured line intensities and latest peer-measured results are within 20%. The biases between our self-broadening coefficients and the ones in HITRAN2020 are within 14%. Their uncertainties are in a range of the 0.63–2.7% and 0.77–5.4%, respectively, which are smaller than the uncertainty range of 10–20% in the HITRAN database. Some of the measured spectral parameters are not recorded in HITRAN. The experimental results in this work are of significant reference in supplementing and correcting the HITRAN spectral parameters of NH3 in the range of 4296–4302 cm–1.

     

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