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中国物理学会期刊

1.1 μm波段水分子的CO2加宽系数

CSTR: 32037.14.aps.71.20220700

CO2-broadened coefficients of water vapor molecule in 1.1 μm band

CSTR: 32037.14.aps.71.20220700
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  • 水分子吸收光谱参数是遥感探测、行星观测应用领域所需的关键基础科学数据. 基于窄线宽外腔半导体激光器和长程吸收池, 测量了室温下9332—722 cm–1波段内, CO2加宽的18条水分子的吸收谱线. 分别使用Voigt线型和quadratic speed-dependent Voigt线型对吸收光谱数据进行拟合, 并获得了这些谱线的CO2加宽系数, quadratic speed-dependent Voigt线型表现出更好的拟合效果. 与HITRAN2020数据库该波段空气加宽系数进行了对比, 两种线型反演获得的水分子CO2加宽系数与空气加宽系数之比的均值分别为1.327和1.454, 验证了利用水分子的空气加宽系数估算CO2加宽系数的方法存在可靠性. 本研究可为近红外波段的火星、金星等大气结构探测技术及相关研究提供可供参考的实测光谱参数数据.

     

    The absorption spectral parameters of water vapor molecules are the key basic scientific data for the remote sensing detection and the planetary observation applications. Based on a narrow line-width external cavity diode laser and a long-path absorption cell, 18 absorption spectral lines of CO2-broadened water vapor molecules in a 9332–9722 cm–1 range at room temperature are measured. To obtain the CO2-broadened water vapor molecule coefficients, the Voigt profile and the quadratic speed-dependent Voigt profile are used to fit the absorption spectrum data. The quadratic speed-dependent Voigt profile shows better fitting capability. Comparing with the air-broadened coefficients of the corresponding region from the HITRAN2020 database, the mean ratios of the CO2-broadened coefficients of water vapor molecules and the air-broadened coefficients obtained from the two models of the line shape are 1.327 and 1.454, respectively, which verifies that the method of estimating the CO2-broadened coefficient by the air-broadened coefficient of water vapor molecules has certain reliability. This study can provide reference data of measured spectral parameters for the detection technology and related research of atmospheric structures of Mars and Venus in the near-infrared region.

     

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