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中国物理学会期刊

基于CRDS和WM-DAS的宽量程免标定H2S体积分数的测量

CSTR: 32037.14.aps.71.20220742

Wide-range and calibration-free H2S volume fraction measurement based on combination of wavelength modulation and direct absorption spectroscopy with cavity ringdown spectroscopy

CSTR: 32037.14.aps.71.20220742
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  • 结合腔衰荡光谱(CRDS)与波长调制-直接吸收光谱(WM-DAS), 建立了一种宽量程、免标定的气体体积分数的检测方法, 具有CRDS高信噪比及WM-DAS快速和可测量绝对体积分数的优点. 基线衰荡时间(τ0)可通过测量谱线中心频率处吸收率(WM-DAS)和衰荡时间(CRDS)计算得到, 无需实时校准, 极大提升了CRDS测量速度. 室温常压下, 在6336.617 cm–1处不同体积分数的H2S测量结果表明, 该方法动态测量范围可扩展到4个数量级以上, 测量精度相比WM-DAS得到了提高, 且检测限可在40 s内达到1 × 10–9.

     

    Combining cavity ring down spectroscopy (CRDS) and wavelength modulated direct absorption spectroscopy (WM-DAS), a wide range and calibration-free gas concentration detection method is established, which has the advantages of high signal-to-noise ratio of CRDS and fast speed and measurable absolute concentration of WM-DAS. The baseline ring down time (τ0) can be calculated by measuring the absorptivity (WM-DAS) and ring down time (CRDS) at the central frequency of the spectral line, without real-time calibration, which greatly improves the speed of CRDS measurement. The measurement results of different H2S concentrations at 6336.617 cm–1 at room temperature and atmospheric pressure show that the dynamic measurement range of this method can be extended to more than 4 orders of magnitude, the measurement accuracy is improved in comparison with WM-DAS, and the detection limit can reach 1 × 10–9 in 40 s.

     

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