搜索

x
中国物理学会期刊

GaN/VSe2范德瓦耳斯异质结电接触特性及调控效应

CSTR: 32037.14.aps.72.20230191

Electrical contact characteristics and regulatory effects of GaN/VSe2 van der Waals heterojunction

CSTR: 32037.14.aps.72.20230191
PDF
HTML
导出引用
  • 降低金属-半导体界面的肖特基势垒并实现欧姆接触对于研发高性能肖特基场效应管非常重要. 鉴于实验上已成功制备GaN及1T-VSe2单层, 本文理论构建GaN/1T-VSe2异质结模型, 并利用基于密度泛函理论的第一性原理研究了其稳定性、肖特基势垒特性及其调控效应. 计算的形成焓及淬火分子动力学模拟表明构建的异质结是稳定的. 研究表明: 本征异质结为p型肖特基接触, 同时发现施加拉伸或压缩应变, 异质结始终保持p型肖特基接触不变, 没有出现欧姆接触. 而施加外电场则不同, 具有明显的调控效应, 较高的正向电场能使异质结从肖特基接触转变为欧姆接触, 较高的反向电场能导致p型肖特基接触转变为n型肖特基接触. 特别是实施化学掺杂, 异质结较容易实现由肖特基接触到欧姆接触的转变, 例如引入B原子能使GaN/1T-VSe2异质结实现典型的欧姆接触, 而C和F原子掺杂, 能使GaN/1T-VSe2异质结实现准欧姆接触. 这些研究对该异质结的实际应用提供了理论参考, 特别是对于研发新型高性能纳米场效应管具有重要意义.

     

    Reducing the Schottky barrier at the metal-semiconductor interface and achieving Ohmic contacts are very important for developing high-performance Schottky field-effect devices. Based on the fact that GaN and 1T-VSe2 monolayers have been successfully prepared experimentally, we theoretically construct a GaN/1T-VSe2 heterojunction model and investigate its stability, Schottky barrier property and its modulation effects by using first-principle method. The calculated formation energy and the molecular dynamics simulations show that the constructed heterojunction is very stable, meaning that it can be realized experimentally. The intrinsic heterojunction holds a p-type Schottky contact and always keeps the same p-type Schottky contact when tensile or compressive strain is applied. But when the external electric field is applied, the situation is different. For example, a higher forward electric field can cause the heterojunction to change from a Schottky contact into an Ohmic contact, and a higher reverse electric field can lead to a variation from a p-type Schottky contact to an n-type Schottky contact. In particular, by implementing chemical doping, the transition from Schottky contact to Ohmic contact can be achieved more easily for the heterojunction. For example, the introduction of B atom enables the GaN/1T-VSe2 heterojunction to realize a typical Ohmic contact, while for C and F atom doping, the GaN/1T-VSe2 heterojunction can achieve a quasi-Ohmic contact. These studies provide a theoretical reference for the practical application of the suggested heterojunction, and are of very important in designing novel high-performance nano-scale electronic devices.

     

    目录

    /

    返回文章
    返回