Inhomogeneous magnetic field is introduced into pulsed laser deposition process, in order to find new properties of diamond-like carbon film grown under magnetic field, thereby offering the theoretical and experimental basis for further enhancing sp³-bond content in this film. Distribution of the magnetic strength and flux lines induced by a rectangular permanent magnet is calculated. And then, flying trace of the carbon ions in the magnetic field is also simulated by the iterative method, which indicates that the carbon ions cannot expand freely and they are confined and accumulate around the center region of the magnet source. Beside the surface interference, the measurement and the fitted results of ellipsometry parameters show that magnetic field exerts an important influence on layer-thickness distribution and optical constant of the pulsed laser deposition-grown diamond-like carbon film. Meanwhile, it is indicated that the inhomogeneity of the layer-thickness distribution and optical constant increase when the magnetic strength is higher. Micro-structure of diamond-like carbon film is affected seriously by magnetic field, which is indicated by Raman spectra. Magnetic field can enhance the local stress in the carbon matrix net, increasing the sp³-bond content. Theoretical research and experimental research both show that a suitable magnetic strength can excite micro-structure of diamond-like carbon film significantly, and the high-quality diamond-like carbon coating with practical application value will be obtained by technological adjustment.