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中国物理学会期刊

石墨烯层数及化学势对近场热二极管热通量与整流效应的协同调控

Synergistic modulation of graphene numbers and chemical potentials for heat flux and rectification effects in near-field thermal diodes

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  • 石墨烯因其电子特性可调且能激发极化激元,在近场热辐射调控方面展现出巨大潜力。本文基于多层石墨烯覆盖碳化硅基底,构建了对称和非对称近场热二极管模型,用以揭示石墨烯层数、化学势及间隙距离对辐射热通量与整流比的协同调控规律。研究结果表明,石墨烯化学势和层数对热通量的调控效果强烈依赖于间隙距离。与无石墨烯覆盖和非对称石墨烯覆盖结构相比,当间隙距离小于300 nm时,对称单层和多层石墨烯覆盖结构可显著增强辐射热通量。在50nm到500nm的间隙范围,热通量随石墨烯层数增加而升高,但其增幅随层数增加逐渐减缓。对于非对称石墨烯覆盖结构,间隙距离越小,石墨烯化学势及层数对热通量的调控作用越显著;当间隙距离超过300 nm时,该调控作用显著减弱,几乎可忽略不计。非对称石墨烯覆盖结构的整流比随间隙距离的增大呈现先增后减的趋势,其最大整流比可达0.155。较小的间隙距离、较低化学势及较少石墨烯层数是提升非对称石墨烯覆盖结构热整流比的有利因素。本研究揭示了石墨烯层数、化学势和近场效应之间的协同调控作用规律,为高性能近场热整流器的设计提供了理论支撑。

     

    Graphene exhibits great potential in near‑field thermal radiation regulation due to its tunable electronic properties and ability to support polariton excitation. In this work, symmetric and asymmetric near‑field thermal diode models composed of multilayer graphene‑covered silicon carbide (SiC) substrates are constructed, and the synergistic regulation of graphene layer number, chemical potential, and gap distance on the radiative heat flux and rectification ratio is systematically investigated. The results show that the modulation effect of graphene chemical potential and layer number on the heat flux strongly depends on the gap distance. Compared with the structure without graphene coating (SiC‑SiC) and the asymmetric graphene‑covered structure (GSiC‑SiC), the symmetric monolayer and multilayer graphene‑covered structures (MGSiC‑MGSiC) significantly enhance the radiative heat flux at small gap distances (d < 300 nm), and heat flux presents a peak as the chemical potential rises. In the gap distance range of 50‑500 nm, the radiative heat flux increases with the graphene layer number, but the enhancement gradually slows down as the layer number further increases. For asymmetric graphene‑covered structures (GSiC‑SiC, MGSiC‑SiC, MGSiC‑GSiC), increasing the chemical potential or the layer number is detrimental to the enhancement of the radiative heat flux at small gap distance (d < 300 nm); at large gap distance (d > 300 nm), the modulation effect of graphene chemical potential and layer number on the heat flux tends to zero. For the asymmetric graphene‑covered structure (MGSiC‑SiC), reducing the chemical potential (0.5 eV, 0.3 eV, 0.1 eV) and decreasing the layer number (from 4 to 1) effectively improve the thermal rectification ratio. Numerical calculations show that when the graphene layer number, chemical potential and gap distance are 1, 0.1 eV, and 30 nm, respectively, the rectification ratio of the MGSiC‑SiC structure reaches 0.155. For the MGSiC‑GSiC structure, as the layer number increases from 1 to 4, the maximum rectification ratio of 0.035 is achieved at 3 layers, 100 nm and a chemical potential of 0.1 eV. For all asymmetric structures (GSiC‑SiC, MGSiC‑SiC, MGSiC‑GSiC), the maximum rectification ratios appear in the near‑field region. These results indicate that a smaller gap distance, lower chemical potential, and fewer graphene layers are favorable for achieving superior thermal rectification performance in asymmetric graphene‑covered structures. This study reveals the synergistic regulation mechanism among graphene layer number, chemical potential, and near‑field effects, providing theoretical guidance for the design of high‑performance near‑field thermal rectifiers.

     

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