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中国物理学会期刊

非晶Ni-P合金的晶化相

CSTR: 32037.14.aps.33.1182

CRYSTALLIZATION PHASES IN AMORPHOUS Ni-P ALLOY

CSTR: 32037.14.aps.33.1182
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  • 利用电镜双倾台倾转Ni12P5晶体以及对Vafaei-Makhsoos发表的数据的分析,证实了由他所提出的三个新的Ni3P相并不存在。从而澄清了非晶Ni-P合金在加热过程中总共有七个晶化相析出:α=5.48?的面心立方亚稳相α,由此相转变生成的六角多型体α1,α2,α3亚稳相,体心四方Ni12P5相,体心四方Ni3P相及Ni固溶体。

     

    Vafaei-Makhsoos claimed to have discovered three new Ni3P phases in crystallized Ni-P amorphous alloy. By analysis of his experimental data as well as our own electron diffraction experiments, it is shown that the various electron diffraction patterns of the so-called new Ni3P phases are in fact all belonging to Ni12P5. Thus it is clear that there are seven crystallization phases in annealed amorphous Ni-P alloys: metastable fcc phase α (α=5.48?), metastable hexagonal polytypes α1,α2,α3 transformed from α, bct Ni12P5, bct Ni3P and Ni solid solution.

     

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