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中国物理学会期刊

Y(Mn1-xCox)12磁结构的中子衍射分析

CSTR: 32037.14.aps.33.850

MAGNETIC STRUCTURE ANALYSIS OF Y(Mn1-xCox)12 BY NEUTRON DIFFRACTION

CSTR: 32037.14.aps.33.850
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  • 在研究Y(Mn1-xCox)12晶体结构的基础上,为了分析这种化合物的磁结构,我们挑选了不同成分的试样,在液氮温度下作了中子衍射测量。实验上测到的磁有序超结构峰可以用YMn12单胞指标化为h十k+l=2n+1。使用各种可能的磁结构模型对数据进行了分析,根据计算强度与观测强度的最佳拟合,得出了Y(Mn1-xCox)12的磁结构随x变化的某些结论。

     

    On the basis of determining the ordering of Co and Mn atoms in the Y(Mn1-xCox)12 alloys, we went on to carry out the neutron diffraction measurement of these compounds at liquid nitrogen temperture to investigate their magnetic structure. Some magnetic superstructure peaks were observed, which can be indexed as h+k+l=2n+1 based on the YMn12-type unit cell. The experimental data were analysed using various possible magnetic structure models. From the best fit between the calculated and observed intensities, it is concluded that: (A) Y(Mn1-xCox)12 are antiferromagnetic structure of noncollinear type for x = 0, 0.3 and 0.4; The arrangement of partial magnetic moments on 8f and 8j sites change into parallel to each other for x = 0.5, 0.6 and 0.67. Whereas the magnetic moments on 8i sites still remain in antiparallel configuration. Moreover, the ratio of ferromagnetic composition increases with the increase of Co concentration x; All magnetic moments on 8i, 8j and 8f sites are parallel to each other in the basal plane of the tetragonal structure for x = 0.8. The sample exhibits ferromagnetism in such a case. (B) As compared with the YMn12, the substitution of Mn with Co leads to an increase of the mean magnetic moment on 8i, 8j and 8f atoms.

     

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