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温控电弧放电法大量制备单壁碳纳米管

赵廷凯 柳永宁

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温控电弧放电法大量制备单壁碳纳米管

赵廷凯, 柳永宁
cstr: 32037.14.aps.53.3961

Large scale synthesis of single-walled carbon nanotubes by an arc-discharge method at controlled temperatures

Zhao Ting-Kai, Liu Yong-Ning
cstr: 32037.14.aps.53.3961
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  • 采用可以控制真空室温度的改进型直流电弧炉,在氮气和氦气(1∶1)混合气氛下,使用Co-Ni(1∶1wt%)合金催化剂,通过控制温度等工艺条件,在容器内壁生成了大量单壁碳纳米管,尤其在阴极与阳极之间有大量的宏观网状薄膜.通过两步纯化方法:在500℃空气中烘烧30min;再用37%盐酸浸泡72h,用去离子水过滤至中性烘干.经SEM,HRTEM,XRD,Raman观察分析,纯化后其纯度高(>95%)、管径均匀(1.24—1.38nm).实验结果表明:温度强烈影响单壁碳纳米管的产量,不同温度下管子的纯度、产量都有差异,在温度为600℃时,其纯度达到70%,产量为12g/h.
    Large amounts of single-wall carbon nanotubes(SWNTs) deposited on all the wall of the chamber have been obtained in helium and nitrogen mixed atmosphere using Co-Ni alloy catalyst with a modified arc furnace which can control the temperature during arcing process. Additionally, there are many weblike deposition products located between the cathode and anode. By twostep purification:the as-grown SWNT was heated in air at 500℃ for 30min, then soaked in 37% hydrochloric acid for 72h and filtered with deionized water. Microanalysis was carried out by Transmission electron microscopy(TEM), high-resolution TEM and Raman spectroscopy. The results obtained indicate that the purified SWNTs have high purity (higher than 95%) and uniform diameter (from 1.24 to 1.38nm).This experiment indicates that the temperature strongly affects the production of SWNT; the production and purity of SWNT increase with temperature. When the temperature is 600℃, the purity is about 70% and the production of SWNT is 12g/h.
    • 基金项目: 陕西省科技计划项目(批准号:2003K07G12)资助的课题
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  • 文章访问数:  8747
  • PDF下载量:  1720
  • 被引次数: 0
出版历程
  • 收稿日期:  2003-12-17
  • 修回日期:  2004-02-23
  • 刊出日期:  2004-11-16

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