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Er0.3Gd0.7VO4晶体红外量子剪裁效应及其在太阳能电池应用上的研究

陈晓波 杨国建 张春林 李永良 廖红波 张蕴芝 陈鸾 王亚非

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Er0.3Gd0.7VO4晶体红外量子剪裁效应及其在太阳能电池应用上的研究

陈晓波, 杨国建, 张春林, 李永良, 廖红波, 张蕴芝, 陈鸾, 王亚非

Infrared quantum-cutting analysis of Er0.3Gd0.7VO4 crystal for solar cell application

Chen Xiao-Bo, Yang Guo-Jian, Zhang Chun-Lin, Li Yong-Liang, Liao Hong-Bo, Zhang Yun-Zhi, Chen Luan, Wang Ya-Fei
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  • 研究了高浓度的Er0.3Gd0.7VO4晶体材料的红外量子剪裁现象,结果发现光激发2H11/2能级和4G11/2能级的4I13/2→4I15/2荧光跃迁的近似的量子剪裁效率η’已达约178.55%和177.61%
    Recently the infrared quantum cutting has achieved an exciting development in enhancing the efficiency of solar cell. The infrared quantum cutting of Er0.3Gd0.7VO4 crystalline is studied in the present paper. It is found that the approximate quantum cutting efficiencies of 1532.5 nm 4I13/2→4I15/2 fluorescence, when the 2H11/2 and 4G11/2 levels are excited, are about 178.55% and 177.61% respectively. Especially, effective three-photon and four-photon infrared quantum cuttings of Er0.3Gd0.7VO4 crystalline excited by visible and near-violet light are found for the first time in the present paper. An interesting "peak - valley" conversion phenomenon in the excitation spectrum is also observed. It is also the first time for us to find the first-order infrared quantum cutting based single species Er3+ ion for Er0.3Gd0.7VO4 crystalline.
    • 基金项目: 国家自然科学基金(批准号: 10674019)资助的课题.
    [1]

    Yang G Z National natural science foundation of China 1995 Optical Physics (Beijing : Science Press) (in Chinese) [杨国桢,等,国家自然科学基金委员会 1995 光物理科学(北京:科学出版社)]

    [2]

    Wegh R T, Donker H, Oskam K D, Meijerink A 1999 Science 283 663

    [3]

    Zhou Y, Feofilov S P, Jeong J Y, D A Keszler, Meltzer R S 2006 Journal of Luminescence 120 265

    [4]

    Presting H, Konle J, Kibbel H, Thonke K, Sauer R 2001 Silicon-Based and Hybrid Optoelectronics III 4293 63

    [5]

    Song Z F, Lian S R, Wang S K 1982 Acta Phys. Sinic. 31 772 (in Chinese) [宋增福、连绍仁、王淑坤 1982 物理学报 31 772] 〖6] Wegh R T, Donker H, Oskam K D, and Meijerink A 1999 Journal of Luminescence 82 93

    [6]

    Ye S, Luo J, Chen J X, Zhu B, Lakshminarayana G, Qiu J R 2008 Optics Express 16 8989

    [7]

    Chen D Q, Wang Y S, Yu Y L, Huang P, Weng F Y 2008 Optics Letters 33 1884

    [8]

    Richards B S 2006 Solar Energy Materials and Solar Cells 90 1189

    [9]

    Vergeer P, Vlugt T J H, Kox M H F, Hertog M I den, van der Eerden J P J M, Meijerink A 2005 Physical Review B 71 014119

    [10]

    Lee T J, Luo L Y, Diau E W G, Chen T M, Cheng B M, Tung C Y 2006 Applied Physics Letters 89 131121

    [11]

    Wang G W, Tang Y, Long C W 1964 Acta Phys. Sin. 20 1178 (in Chinese)[王国文、汤 沂、龙纯玮 1964 物理学报 20 1178]

    [12]

    Carnall W T, Fieldd R, Rajnank K T 1968 J. Chem. Phys. 49 4424

    [13]

    Zhang Q Y, Liang X F 2007 Journal of the Society for Information Display 16 755

    [14]

    Zaguniennyi A I, Ostoumov V G, Shcherbakov I A, Jensen T, Meyn J P, Huber G 1992 Sov. J. Quant. Electron. 22 1071

    [15]

    Tzenga H Y, Cheng B M, Chen T M 2007 Journal of Luminescence 122-123 917

    [16]

    Ni P G, Zhang S Z, Ji P W 2008 Bulletin of National Natural Science Foundation of China 5 301 (in Chinese)[倪培根、张守著、汲培文 2008 中国科学基金 5 301]

    [17]

    Wang N Y, Zhang L 2001 Acta Phys. Sin. 50 693(in Chinese) [王乃彦\,张 路 2001 物理学报 50 693]

    [18]

    Reisfeld R 1977 Lasers and excited states of rare-earth (New York: Springer-Verlag, Berlin Heidelberg,)

    [19]

    Chen X Y, Luo Z D 1998 Chin.Phys. 7 773

    [20]

    Xiao S G, Yang X L, and Ding J W 2009 Acta Phys. Sin. 58 3812(in Chinese)[肖思国\,阳效良\,丁建文 2009 物理学报 58 3812]

    [21]

    Xu X R, Shu M Z 2003 Science of Luminescence and Luminescent Material (Beijing: The Publish Center of Material Science and Engineering)(in Chinese) [徐叙瑢\,苏勉曾 2003 发光学与发光材料 (北京: 材料科学与工程出版中心)]

    [22]

    Zhou J, Ren Z, Zhai T R 2009 Acta Phys. Sin. 58 3208(in Chinese)[周 静\,任 芝\,翟天瑞 2009 物理学报 58 3208]

    [23]

    Ogata K, Matsui T, Isomura M, Kondo M 2006 Journal of Non-Crystalline Solids 352 1255

    [24]

    Chen Z J, Chen H Y, Gong Q H 1999 Acta Phys. Sin. 48 477(in Chinese)[陈志坚、陈慧英、龚旗煌 1999 物理学报 48 477]

    [25]

    Zhang Q Y, Yang C H, Pan Y X 2007 Applied Physics Letters 90 021107

    [26]

    Dai Z W, Yang H G, Zu N N 2007 Chin. Phys. 16 1650

    [27]

    Wang E G, Guo Y, Zhang Y F, Oe T Z, Bao X Y, Tang Z, Zhang L X, Zhu W G, Niu Q, Qiu Z Q, Jia J F, Zhao Z X 2004 Science 306 5703

  • [1]

    Yang G Z National natural science foundation of China 1995 Optical Physics (Beijing : Science Press) (in Chinese) [杨国桢,等,国家自然科学基金委员会 1995 光物理科学(北京:科学出版社)]

    [2]

    Wegh R T, Donker H, Oskam K D, Meijerink A 1999 Science 283 663

    [3]

    Zhou Y, Feofilov S P, Jeong J Y, D A Keszler, Meltzer R S 2006 Journal of Luminescence 120 265

    [4]

    Presting H, Konle J, Kibbel H, Thonke K, Sauer R 2001 Silicon-Based and Hybrid Optoelectronics III 4293 63

    [5]

    Song Z F, Lian S R, Wang S K 1982 Acta Phys. Sinic. 31 772 (in Chinese) [宋增福、连绍仁、王淑坤 1982 物理学报 31 772] 〖6] Wegh R T, Donker H, Oskam K D, and Meijerink A 1999 Journal of Luminescence 82 93

    [6]

    Ye S, Luo J, Chen J X, Zhu B, Lakshminarayana G, Qiu J R 2008 Optics Express 16 8989

    [7]

    Chen D Q, Wang Y S, Yu Y L, Huang P, Weng F Y 2008 Optics Letters 33 1884

    [8]

    Richards B S 2006 Solar Energy Materials and Solar Cells 90 1189

    [9]

    Vergeer P, Vlugt T J H, Kox M H F, Hertog M I den, van der Eerden J P J M, Meijerink A 2005 Physical Review B 71 014119

    [10]

    Lee T J, Luo L Y, Diau E W G, Chen T M, Cheng B M, Tung C Y 2006 Applied Physics Letters 89 131121

    [11]

    Wang G W, Tang Y, Long C W 1964 Acta Phys. Sin. 20 1178 (in Chinese)[王国文、汤 沂、龙纯玮 1964 物理学报 20 1178]

    [12]

    Carnall W T, Fieldd R, Rajnank K T 1968 J. Chem. Phys. 49 4424

    [13]

    Zhang Q Y, Liang X F 2007 Journal of the Society for Information Display 16 755

    [14]

    Zaguniennyi A I, Ostoumov V G, Shcherbakov I A, Jensen T, Meyn J P, Huber G 1992 Sov. J. Quant. Electron. 22 1071

    [15]

    Tzenga H Y, Cheng B M, Chen T M 2007 Journal of Luminescence 122-123 917

    [16]

    Ni P G, Zhang S Z, Ji P W 2008 Bulletin of National Natural Science Foundation of China 5 301 (in Chinese)[倪培根、张守著、汲培文 2008 中国科学基金 5 301]

    [17]

    Wang N Y, Zhang L 2001 Acta Phys. Sin. 50 693(in Chinese) [王乃彦\,张 路 2001 物理学报 50 693]

    [18]

    Reisfeld R 1977 Lasers and excited states of rare-earth (New York: Springer-Verlag, Berlin Heidelberg,)

    [19]

    Chen X Y, Luo Z D 1998 Chin.Phys. 7 773

    [20]

    Xiao S G, Yang X L, and Ding J W 2009 Acta Phys. Sin. 58 3812(in Chinese)[肖思国\,阳效良\,丁建文 2009 物理学报 58 3812]

    [21]

    Xu X R, Shu M Z 2003 Science of Luminescence and Luminescent Material (Beijing: The Publish Center of Material Science and Engineering)(in Chinese) [徐叙瑢\,苏勉曾 2003 发光学与发光材料 (北京: 材料科学与工程出版中心)]

    [22]

    Zhou J, Ren Z, Zhai T R 2009 Acta Phys. Sin. 58 3208(in Chinese)[周 静\,任 芝\,翟天瑞 2009 物理学报 58 3208]

    [23]

    Ogata K, Matsui T, Isomura M, Kondo M 2006 Journal of Non-Crystalline Solids 352 1255

    [24]

    Chen Z J, Chen H Y, Gong Q H 1999 Acta Phys. Sin. 48 477(in Chinese)[陈志坚、陈慧英、龚旗煌 1999 物理学报 48 477]

    [25]

    Zhang Q Y, Yang C H, Pan Y X 2007 Applied Physics Letters 90 021107

    [26]

    Dai Z W, Yang H G, Zu N N 2007 Chin. Phys. 16 1650

    [27]

    Wang E G, Guo Y, Zhang Y F, Oe T Z, Bao X Y, Tang Z, Zhang L X, Zhu W G, Niu Q, Qiu Z Q, Jia J F, Zhao Z X 2004 Science 306 5703

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  • 被引次数: 0
出版历程
  • 收稿日期:  2009-12-18
  • 修回日期:  2010-03-02
  • 刊出日期:  2010-11-15

Er0.3Gd0.7VO4晶体红外量子剪裁效应及其在太阳能电池应用上的研究

  • 1. (1)北京师范大学,应用光学北京重点实验室,北京 100875; (2)中国科学院物理研究所,北京 100080
    基金项目: 

    国家自然科学基金(批准号: 10674019)资助的课题.

摘要: 研究了高浓度的Er0.3Gd0.7VO4晶体材料的红外量子剪裁现象,结果发现光激发2H11/2能级和4G11/2能级的4I13/2→4I15/2荧光跃迁的近似的量子剪裁效率η’已达约178.55%和177.61%

English Abstract

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