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采用自由落体和单辊急冷技术研究了三元Fe62.1Sn27.9Si10偏晶合金的相分离和组织形成规律,理论分析了两种快速凝固条件下合金的传热特性.自由落体条件下,由于Marangoni迁移和表面偏析势的作用,液滴凝固组织主要形成富Sn相包裹富Fe相的两层壳核结构.随着液滴直径减小,冷却速率和温度梯度增大,促进偏晶胞快速生长.在单辊急冷条件下,随着辊速的增大,冷却速率从1.1107增大至6.5107 K/s,合金熔体内部的液相流动和相分离受到抑制,凝固组织发生九层结构两层结构无分层结构的转变.同时,凝固过程中FeSn+L2FeSn2包晶反应受到抑制,形成与自由落体条件下不同的相组成.EDS分析显示,Fe相在快速凝固过程中发生显著溶质截留效应.
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关键词:
- Fe-Sn-Si偏晶合金 /
- 相分离 /
- 快速凝固 /
- 溶质截留
Ternary Fe62.1Sn27.9Si10 monotectic alloy is rapidly solidified in drop tube with the freely-falling-body techniqual and with melt spinning method separately. The phase separation, the microstructure characteristics, and the heat transfer of this alloy are investigated theoretically. Under free fall condition, the core-shell structure with two layers is formed because of Marangoni migration and surface segregation, where the Sn-rich phase is always located at droplet surface and the Fe-rich phase in the center. With the decrease of droplet diameter, both cooling rate and temperature gradient increase quickly, which facilitates the rapid growth of monotectic cell. With the increase of wheel speed, the cooling rate of alloy ribbon increases from 1.1107 to 6.5107 K/s, the fluid flow and the phase separation are suppressed to a great extent, and the nine layers two layers no layer structural transition occurs during the rapid solidification of Fe62.1Sn27.9Si10 alloy obtained by the melt spinning method. Meanwhile, the FeSn+L2FeSn2 peritectic transformation is also suppressed, thus resulting in different phase constitutions as compared with the case of free fall condition. The energy dispersive spectroscopy (EDS) analysis reveals that the Fe phase exhibits a conspicuous solute trapping effect during rapid solidification.-
Keywords:
- Fe-Sn-Si monotectic alloy /
- phase separation /
- rapid solidification /
- solute trapping
[1] Gonnella G, Lamura A, Piscitelli A, Tiribocchi A 2010 Phys. Rev. E 82 046302
[2] [3] Chung H J, Composto R J 2004 Phys. Rev. Lett. 92 185704
[4] [5] Wang W L, Zhang X M, Qin H Y, Wei B 2009 Phil. Mag. Lett. 89 11
[6] Mirkovi Ac' D, Grbner J, Schmid-Fetzer R 2008 Acta Mater. 56 5214
[7] [8] Puri S, Binder K 2001 Phys. Rev. Lett. 86 1797
[9] [10] Li H L, Zhao J Z 2008 Appl. Phys. Lett. 92 241902
[11] [12] Liu X R, Wang N, Wei B B 2005 Acta Phys. Sin. 54 1671 (in Chinese) [刘向荣、 王 楠、 魏炳波 2005 物理学报 54 1671]
[13] [14] [15] Zhou F M, Sun D K, Zhu M F 2010 Acta Phys. Sin. 59 3394 (in Chinese) [周丰茂、 孙东科、 朱鸣芳 2010 物理学报 59 3394] 〖9] Pawar N, Bohidar H B 2010 Phys. Rev. E 82 036107
[16] [17] [18] Kaban I G, Hoyer W 2008 Phys. Rev. B 77 125426
[19] Das S K, Puri S 2002 Phys. Rev. E 65 026141
[20] [21] Raghavan V 1987 Phase Diagram of Ternary Iron Alloys (U.S.A: ASM International) p1168
[22] [23] [24] Rogers J R, Davis R H 1990 Metall. Mater. Trans. A 21 59
[25] Bird R B, Stewart W E, Lightfoot E N 2002 Transport Phenomena (New York: John Wiley and Sons Inc) p863
[26] [27] [28] Gale W F, Smithells C J, Totemeier T C 2004 Smithells Metals Reference Book (Oxford: Elsevier Butterworth-Heinemann) p8-1
[29] [30] Xu J F, Wei B B 2004 Acta Phys. Sin. 53 1909 (in Chinese) [徐锦锋、 魏炳波 2004 物理学报 53 1909]
[31] Poirier D, Salcudean M 1988 J. Heat Transfer 110 56
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[1] Gonnella G, Lamura A, Piscitelli A, Tiribocchi A 2010 Phys. Rev. E 82 046302
[2] [3] Chung H J, Composto R J 2004 Phys. Rev. Lett. 92 185704
[4] [5] Wang W L, Zhang X M, Qin H Y, Wei B 2009 Phil. Mag. Lett. 89 11
[6] Mirkovi Ac' D, Grbner J, Schmid-Fetzer R 2008 Acta Mater. 56 5214
[7] [8] Puri S, Binder K 2001 Phys. Rev. Lett. 86 1797
[9] [10] Li H L, Zhao J Z 2008 Appl. Phys. Lett. 92 241902
[11] [12] Liu X R, Wang N, Wei B B 2005 Acta Phys. Sin. 54 1671 (in Chinese) [刘向荣、 王 楠、 魏炳波 2005 物理学报 54 1671]
[13] [14] [15] Zhou F M, Sun D K, Zhu M F 2010 Acta Phys. Sin. 59 3394 (in Chinese) [周丰茂、 孙东科、 朱鸣芳 2010 物理学报 59 3394] 〖9] Pawar N, Bohidar H B 2010 Phys. Rev. E 82 036107
[16] [17] [18] Kaban I G, Hoyer W 2008 Phys. Rev. B 77 125426
[19] Das S K, Puri S 2002 Phys. Rev. E 65 026141
[20] [21] Raghavan V 1987 Phase Diagram of Ternary Iron Alloys (U.S.A: ASM International) p1168
[22] [23] [24] Rogers J R, Davis R H 1990 Metall. Mater. Trans. A 21 59
[25] Bird R B, Stewart W E, Lightfoot E N 2002 Transport Phenomena (New York: John Wiley and Sons Inc) p863
[26] [27] [28] Gale W F, Smithells C J, Totemeier T C 2004 Smithells Metals Reference Book (Oxford: Elsevier Butterworth-Heinemann) p8-1
[29] [30] Xu J F, Wei B B 2004 Acta Phys. Sin. 53 1909 (in Chinese) [徐锦锋、 魏炳波 2004 物理学报 53 1909]
[31] Poirier D, Salcudean M 1988 J. Heat Transfer 110 56
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