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为进一步揭示硫系玻璃基掺Er3+微结构光纤对于中红外波段信号的放大特性, 采用熔融淬火法研制了Er3+离子掺杂的Ga5Ge20Sb10S65硫系玻璃, 测试了玻璃样品的吸收光谱和2.7 m波段荧光光谱, 利用Judd-Ofelt和Futchbauer-Ladenburg理论分别计算得到了Er3+离子的辐射跃迁概率、辐射寿命以及2.7 m波段受激发射截面. 在此基础上, 建立了一个980 nm抽运下该玻璃基掺Er3+微结构光纤2.7 m波段中红外信号的放大模型, 理论上研究了其作为2.7 m波段中红外信号增益介质时的光放大特性. 结果显示, 硫系玻璃基掺Er3+微结构光纤具有优异的高增益和宽带放大品性. 在200 mW抽运功率激励下的100 cm光纤长度上, 最大小信号增益超过了40 dB, 高于30 dB信号增益的放大带宽达到了120 nm (26962816 nm). 研究表明, Ga5Ge20Sb10S65硫系玻璃基掺Er3+微结构光纤是一种理想的可应用于2.7 m波段中红外宽带放大器的增益介质.In order to demonstrate the characteristics of chalcogenide glass Er3+-doped microstructured optical fiber (MOF) amplifying the mid-infrared band signal, Er3+-doped Ga5Ge20Sb10S65 chalcogenide glass is prepared with high temperature melt-quenching method. The absorption spectrum and 2.7 m band fluorescence spectrum of glass sample are measured, and the spectroscopic parameters such as radiative transition probability, radiative lifetime and 2.7 m band stimulated emission cross-section of Er3+ ion are calculated and analyzed according to the Judd-Ofelt and Futchbauer-Ladenburg theories. The 2.7 m band mid-infrared signal amplifying model of Ga5Ge20Sb10S65 chalcogenide glass Er3+-doped MOF under the excitation of 980 nm is presented, and the amplifying characteristics of 2.7 m-band mid-infrared signals for chalcogenide glass Er3+-doped MOF are investigated theoretically. The results show that the chalcogenide glass Er3+-doped MOF exhibits a higher signal gain and very broad gain spectrum: its maximal gain of small signal exceeds 40 dB and amplifying bandwidth of higher than 30 dB gain reaches about 120 nm (26962816 nm) for a 100 cm long chalcogenide glass erbium-doped MOF with a pump power of 200 mW. The theoretical studies indicate that the Ga5Ge20Sb10S65 chalcogenide glass Er3+-doped MOF is an excellent gain medium which can be applied to broadband amplifiers in the mid-infrared wavelength region.
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[10] Liu S, Li S G, Fu B, Zhou H S, Feng R P 2011 Acta Phys. Sin. 60 034217 (in Chinese) [刘硕, 李曙光, 付博, 周洪松, 冯荣普 2011 物理学报 60 034217]
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[13] Judd B R 1962 Phy. Rev. 127 750
[14] Ofelt G S 1962 J. Chem. Phys. 37 511
[15] Jiassi I, Elhouichet H, Ferid M, Barthou C 2010 J. Lumin. 130 2394
[16] Hayashi H, Tanabe S, Sugimoto N 2008 J. Lumin. 128 333
[17] Chen Y J, Huang Y D, Huang M L, Chen R P, Luo Z D 2004 Opt. Mater. 25 271
[18] Tikhomirov V K, Méndez-Ramos J, Rodriguez V D, Furniss D, Seddon A B 2006 Opt. Mater. 28 1143
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[1] Ma J Y, Fang X, Kamran M, Zhao H Y, Bi C Z, Zhao B R, Qiu X G 2008 Chin. Phys. B 17 3313
[2] Guo H T, Lu M, Tao G M, Feng L, Peng B 2009 J. Chin. Ceram. Soc. 37 2150 (in Chinese) [郭海涛, 陆敏, 陶光明, 冯雷, 彭波 2009 硅酸盐学报 37 2150]
[3] Gan F X 1991 J. Infrared Millim. W. 10 415 (in Chinese) [干福喜 1991 红外与毫米波学报 10 415]
[4] Song B A, Dai S X, Xu T F, Nie Q H, Shen X, Wang X S, Lin C G 2011 Acta Phys. Sin. 60 084217 (in Chinese) [宋宝安, 戴世勋, 徐铁峰, 聂秋华, 沈 祥, 王训四, 林常规 2011 物理学报 60 084217]
[5] Nie Q H, Wang G X, Wang X S, Xu T F, Dai S X, Shen X 2010 Acta Phys. Sin. 59 7949 (in Chinese) [聂秋华, 王国祥, 王训四, 徐铁峰, 戴世勋, 沈祥 2010 物理学报 59 7949]
[6] El-Amraoui M, Gadret G, Jules J C, Fatome J, Fortier C, Désévédavy F, Skripatchev I, Messaddeq Y, Troles J, Brilland L, Gao W, Suzuki T, Ohishi Y, Smektala F 2010 Opt. Express 18 26655
[7] Brilland L, Charpentier F, Troles J, Bureau B, Boussard-Plédel C, Adam J L, Méchin D, Trégoat D 2009 Proc. SPIE 7503 581
[8] Wang D D, Wang L L 2010 Acta Phys. Sin. 59 3255 (in Chinese) [王豆豆, 王丽莉 2010 物理学报 59 3255]
[9] Liu X Y, Zhang F D, Zhang M, Ye P D 2007 Acta Phys. Sin. 56 301 (in Chinese) [刘小毅, 张方迪, 张民, 叶培大 2007 物理学报 56 301]
[10] Liu S, Li S G, Fu B, Zhou H S, Feng R P 2011 Acta Phys. Sin. 60 034217 (in Chinese) [刘硕, 李曙光, 付博, 周洪松, 冯荣普 2011 物理学报 60 034217]
[11] De Sario, Mescia L, Prudenzano F, Smektala F, Deseveday F, Nazabal V, Troles J, Brilland L 2009 Opt. Fiber Technol. 41 99
[12] Prudenzano F, Mescia L, Allegretti L, De Sario M, Smektala F, Moizan V, Nazabal V, Troles J, Doualan J L, Canat G, Adam J L, Boulard B 2009 Opt. Mater. 31 1292
[13] Judd B R 1962 Phy. Rev. 127 750
[14] Ofelt G S 1962 J. Chem. Phys. 37 511
[15] Jiassi I, Elhouichet H, Ferid M, Barthou C 2010 J. Lumin. 130 2394
[16] Hayashi H, Tanabe S, Sugimoto N 2008 J. Lumin. 128 333
[17] Chen Y J, Huang Y D, Huang M L, Chen R P, Luo Z D 2004 Opt. Mater. 25 271
[18] Tikhomirov V K, Méndez-Ramos J, Rodriguez V D, Furniss D, Seddon A B 2006 Opt. Mater. 28 1143
[19] Jackson S D, King T A, Pollnau M 2000 J. Mod. Opt. 47 1987
[20] Tian Y, Xu R R, Zhang L Y 2011 Opt. Lett. 36 109
[21] Brechet F, Marcou J, Pagnoux D, Roy P 2000 Opt. Fiber Technol. 6 181
[22] Kadono K, Yazawa T, Jiang S, Porque J, Hwang B C, Peyghambarian N 2003 J. Non-Crysta Solids 331 79
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