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一维石墨烯超晶格上的氢吸附

黄向前 林陈昉 尹秀丽 赵汝光 王恩哥 胡宗海

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一维石墨烯超晶格上的氢吸附

黄向前, 林陈昉, 尹秀丽, 赵汝光, 王恩哥, 胡宗海

Hydrogen adsorption on one-dimensional graphene superlattices

Huang Xiang-Qian, Lin Chen-Fang, Yin Xiu-Li, Zhao Ru-Guang, Wang En-Ge, Hu Zong-Hai
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  • 通过化学气相沉积法在一种典型的高指数面铜(410)-氧上制备出了一维石墨烯超晶格,并利用拉曼光谱(Raman)、低能电子衍射(LEED)、扫描隧道显微术(STM)等方法研究了氢原子在该超晶格上的吸附. 实验结果揭示了由于超晶格的调制作用所引起的无缺陷石墨烯区域的选择性吸附,氢原子优先吸附在石墨烯超晶格一维周期中的相同部位. 这一发现为进一步通过一维超晶格调控石墨烯的性质提供了更多可能. 在石墨烯上的吸附氢原子除了单个或成对存在之外,实验还首次观察到一种新的三氢原子位型.
    One-dimensional (1D) graphene superlattices were formed on a prototypical high index surface-Cu(410)-O. Atomic hydrogen adsorption on the superlattice was studied by using Raman spectroscopy, low-energy electron diffraction (LEED) and scanning tunneling microscopy (STM). Selective H adsorption due to the 1D modulation from the Cu substrate was observed in defect-free graphene area. Most H adatoms occupy the same positions in the 1D graphene superlattice stripes, as revealed by STM. This opens the possibility for further graphene property tuning through 1D superlattices. In addition to H monomers and dimers, a new type of trimer configuration was also observed.
    • 基金项目: 国家重点基础研究发展计划(批准号:2012CB921300)和国家自然科学基金(批准号:11074005,91021007)资助的课题.
    • Funds: Project supported by the National Basic Research Program of China (Grant No. 2012CB921300), and the National Natural Science Foundation of China (Grant Nos. 11074005, 91021007).
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  • [1]

    Novoselov K S, Geim A K, Morozov S V, Jiang D, Zhang Y, Dubonos S V, Grigorieva I V, Firsov A A 2004 Science 306 666

    [2]

    Zhang Y B, Tan Y W, Stormer H L, Kim P 2005 Nature 438 201

    [3]
    [4]

    Li X S, Cai W W, An J, Kim S, Nah J, Yang D X, Piner R, Velamakanni A, Jung I, Tutuc E, Banerjee S K, Colombo L, Ruoff R S 2009 Science 324 1312

    [5]
    [6]
    [7]

    Yin X L, Li Y L, Ke F, Lin C F, Zhao H B, Gan L, Luo Z T, Zhao R G, Heinz T F, Hu Z H 2014 Nano Res. (in press) DOI:10.1007/s12274-014-0521-0

    [8]
    [9]

    Pan Y, Shi D X, Gao H J 2007 Chin. Phys. 16 3151

    [10]

    Gan L, Luo Z T 2013 ACS Nano 7 9480

    [11]
    [12]
    [13]

    Huang L, Xu W Y, Que Y D, Pan Y, Gao M, Pan L D, Guo H M, Wang Y L, Du S X, Gao H J 2012 Chin. Phys. B 21 088102

    [14]

    Ouyang F P, Chen L J, Xiao J, Zhang H 2011 Chin. Phys. Lett. 28 047304

    [15]
    [16]

    Ma L, Tan Z B, Tan C L, Liu G T, Yang C L, Lu L 2011 Acta Phys. Sin. 60 107302(in Chinese) [马丽, 谭振兵, 谭长玲, 刘广同, 杨昌黎, 吕力 2011 物理学报 60 107302]

    [17]
    [18]
    [19]

    Wei X L, Chen Y P, Wang R Z, Zhong J X 2013 Acta Phys. Sin. 62 57101(in Chinese) [魏晓林, 陈元平, 王如志, 钟建新 2013 物理学报 62 57101]

    [20]
    [21]

    Zeng M, Wang W L, Bai X D 2013 Chin. Phys. B 22 098105

    [22]

    Ke F, Yin X L, Tong N, Lin C F, Liu N, Zhao R G, Fu L, Liu Z F, Hu Z H 2014 Chin. Phys. B 23 116801

    [23]
    [24]
    [25]

    Elias D C, Nair R R, Mohiuddin T M G, Morozov S V, Blake P, Halsall M P, Ferrari A C, Boukhvalov D W, Katsnelson M I, Geim A K, Novoselov K S 2009 Science 323 610

    [26]

    Robinson J T, Burgess J S, Junkermeier C E, Badescu S C, Reinecke T L, Perkins F K, Zalalutdniov M K, Baldwin J W, Culbertson J C, Sheehan P E, Snow E S 2010 Nano Lett. 10 3001

    [27]
    [28]

    Cheng S H, Zou K, Okino F, Gutierrez H R, Gupta A, Shen N, Eklund P C, Sofo J O, Zhu J 2010 Phys. Rev. B 81 205435

    [29]
    [30]

    Balog R, Jorgensen B, Nilsson L, Andersen M, Rienks E, Bianchi M, Fanetti M, Laegsgaard E, Baraldi A, Lizzit S, Sljivancanin Z, Besenbacher F, Hammer B, Pedersen T G, Hofmann P, Hornekaer L 2010 Nat. Mater. 9 315

    [31]
    [32]

    Yazyev O V 2010 Rep. Prog. Phys. 73 056501

    [33]
    [34]
    [35]

    Park C-H, Yang L, Son Y-W, Cohen M L, Louie S G 2008 Nat. Phys. 4 213

    [36]

    Yankowitz M, Xue J M, Cormode D, Sanchez-Yamagishi J D, Watanabe K, Taniguchi T, Jarillo-Herrero P, Jacquod P, LeRoy B J 2012 Nat. Phys. 8 382

    [37]
    [38]

    Liu Y, Yao J, Chen C, Miao L, Jiang J J 2013 Acta Phys. Sin. 62 63601(in Chinese) [刘源, 姚洁, 陈驰, 缪灵, 江建军 2013 物理学报 62 63601]

    [39]
    [40]

    Pan H Z, Wang Y L, He K H, Wei M Z, Ouyang Y, Chen L 2013 Chin. Phys. B 22 067101

    [41]
    [42]
    [43]

    Balakrishnan J, Kok Wai Koon G, Jaiswal M, Castro Neto A H, Ozyilmaz B 2013 Nat. Phys. 9 284

    [44]
    [45]

    Lin Y, Ding F, Yakobson B I 2008 Phys. Rev. B 78 041402

    [46]
    [47]

    Guisinger N P, Rutter G M, Crain J N, First P N, Stroscio J A 2009 Nano Lett. 9 1462

    [48]

    Balog R, Jrgensen B, Wells J, Lgsgaard E, Hofmann P, Besenbacher F, Hornekr L 2009 J. Am. Chem. Soc. 131 8744

    [49]
    [50]
    [51]

    Ruffieux P, Grning O, Bielmann M, Mauron P, Schlapbach L, Grning P 2002 Phys. Rev. B 66 245416

    [52]
    [53]

    Lin C F, Huang X Q, Ke F, Jin C H, Tong N, Yin X L, Gan L, Guo X F, Zhao R G, Yang W S, Wang E G, Hu Z H 2014 Phys. Rev. B 89 085416

    [54]
    [55]

    Canado L G, Jorio A, Ferreira E H M, Stavale F, Achete C A, Capaz R B, Moutinho M V O, Lombardo A, Kulmala T S, Ferrari A C 2011 Nano Lett. 11 3190

    [56]
    [57]

    Eckmann A, Felten A, Mishchenko A, Britnell L, Krupke R, Novoselov K S, Casiraghi C 2012 Nano Lett. 12 3925

    [58]

    Hornekr L, Xu W, Otero R, Lgsgaard E, Besenbacher F 2007 Chem. Phys. Lett. 446 237

    [59]
    [60]

    Sofo J O, Chaudhari A S, Barber G D 2007 Phys. Rev. B 75 153401

    [61]
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出版历程
  • 收稿日期:  2014-05-06
  • 修回日期:  2014-05-30
  • 刊出日期:  2014-10-05

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