Al3+/Mo6+双离子取代ZrV2O7中Zr4+/V5+实现近零膨胀

袁保合; 曹文思; 葛向红; 程永光; 刘献省; 梁二军

doi:10.7498/aps.66.076501

摘要

采用固相烧结法制备了Zr1-xAlxV2-xMoxO7（0 x 0.9），并通过调整Al3+/Mo6+对ZrV2O7中的Zr4+/V5+离子替代量来实现近零膨胀.对于较小的x值（x 0.3），材料保持了与ZrV2O7相同的立方相结构.随着Al3+/Mo6+替代量的增加，（Al/Zr）-和（Mo/V）+之间的库仑相互作用逐渐加强，这种库仑相互作用导致材料中未发生畸变的立方相晶体结构逐渐减少.当x 0.7时，材料中立方相晶体结构完全消失.在425750 K温度区间内，Zr0.5Al0.5V1.5Mo0.5O7展示出近零膨胀性质（-0.3910-6 K-1）.Zr0.5Al0.5V1.5Mo0.5O7的低热膨胀性能可能与Al3+/Mo6+对ZrV2O7中Zr4+/V5+部分替代引起部分晶体结构发生的畸变及其对未替代部分的晶格结构的影响有关.

关键词:

Abstract

Zr1-xAlxV2-xMoxO7 (0 x 0.9) is developed by the solid state method, and the near-zero thermal expansion is realized by adjusting the quantity of substitution of Al3+/Mo6+ for Zr4+/V5+ in ZrV2O7. For smaller x values (x 0.3), the samples remain the same cubic structure as that of ZrV2O7. The Coulomb interaction between (Al/Zr)- and (Mo/V)+ increases gradually with increasing the quantity of dual-ion substitution of Al3+/Mo6+ for Zr4+/V5+ in ZrV2O7, which reduces the fraction of the distortionless cubic structure in the sample. For x 0.7, the cubic structures could not be found. For Zr0.5Al0.5V1.5Mo0.5O7, near-zero thermal expansion is obtained in a temperature range from 425 to 750 K (-0.3910-6 K-1). The mechanism of low thermal expansion of Zr0.5Al0.5V1.5Mo0.5O7 could relate to the distortion of crystal structure due to partial substitution of Al3+/Mo6+ for Zr4+/V5+ in ZrV2O7 and the effect of the substitution on the unsubstituted lattice.

Keywords:

作者及机构信息

1.
华北水利水电大学电力学院, 郑州 450011;

2.
中原工学院理学院, 郑州 450007;

3.
河南工程学院理学院分析测试中心, 郑州 451191;

4.
河南大学光伏材料省重点实验室, 开封 475004;

5.
郑州大学物理工程学院, 教育部材料物理重点实验室, 郑州 450052

通信作者: 梁二军, ejliang@zzu.edu.cn

基金项目: 国家自然科学基金（批准号：11574276）资助的课题.

Authors and contacts

1.
North China University of Water Resources and Electric Power, Zhengzhou 450011, China;

2.
College of Science, Zhongyuan University of Technology, Zhengzhou 450007, China;

3.
College of Science, Center of Analysis and Testing of Henan Institute of Engineering, Zhengzhou 451191, China;

4.
Henan Key Laboratory of Photovoltaic Materials, Henan University, Kaifeng 475004, China;

5.
School of Physical Science and Engineering and Key Laboratory of Materials Physics of Ministry of Education of China, Zhengzhou University, Zhengzhou 450052, China

Corresponding author: Liang Er-Jun, ejliang@zzu.edu.cn

Funds: Project supported by the National Natural Science Foundation of China (Grant No. 11574276).

参考文献

[1]	Chen J, Wang F F, Huang Q Z, Hu L, Song X P, Deng J X, Yu R B, Xing X R 2013 Sci. Rep. 3 2458
[2]	Yan J, Sun Y, Wen Y C, Chu L H, Wu M M, Huang Q Z, Wang C, Lynn J W, Chen Y L 2014 Inorg. Chem. 53 2317
[3]	Yao W J, Jiang X X, Huang R J, Li W, Huang C J, Lin Z S, Li L F, Chen C T 2014 Chem. Commun. 50 13499
[4]	Closmann C, Sleight A W, Hargarth J C 1998 J. Solid State Chem. 139 424
[5]	Bridges F, Keiber T, Juhas P, Billinge S J L, Sutton L, Wilde J, Kowach G R 2014 Phys. Rev. Lett. 112 045505
[6]	Liu Q Q, Yu Z Q, Chen G F, Yao J L, Sun X J, Cheng X N, Yang J 2014 Ceram. Int. 40 8195
[7]	Liu X S, Cheng F X, Wang J Q, Song W B, Yuan B H, Liang E J 2013 J. Alloys Compd. 553 1
[8]	Khosrovani N, Sleight A W 1997 J. Solid State Chem. 132 355
[9]	Khosrovani N, Korthuis V, Sleight A W 1996 Inorg. Chem. 35 485
[10]	Withers R L, Evans J S O, Hanson J, Sleight A W 1998 J. Solid State Chem. 137 161
[11]	Withers R L, Tabira Y, Evans J S O, King I J, Sleight A W 2001 J. Solid State Chem. 157 186
[12]	Carlson S, Andersen A M K 2001 J. Appl. Crystallogr. 34 7
[13]	Hemamala U L C, El-Ghussein F, Muthu D V S, Andersen A M K, Carlson S, Ouyang L, Kruger M B 2007 Solid State Commun. 141 680
[14]	Ge X H, Mao Y C, Li L, Li L P, Yuan N, Cheng Y G, Guo J, Chao M J, Liang E J 2016 Chin. Phys. Lett. 33 046503
[15]	Song W B, Wang J Q, Li Z Y, Liu X S, Yuan B H, Liang E J 2014 Chin. Phys. B 23 066501
[16]	Li Q J, Yuan B H, Song W B, Liang E J, Yuan B 2012 Chin. Phys. B 21 046501
[17]	Chu L H, Wang C, Sun Y, Li M C, Wan Z P, Wang Y, Dou S Y, Chu Y 2015 Chin. Phys. Lett. 32 047501
[18]	Guo X G, Lin J C, Tong P, Wang M, WU Y, Yang C, Song B, Liu S, Sun Y P 2015 Appl. Phys. Lett. 107 202406
[19]	Wang F F, Xie Y, Chen J, Fu H G, Xing X R 2013 Appl. Phys. Lett. 103 221901
[20]	Hu P H, Chen J, Sun C, Deng J X, Xing X R, Snyder R L 2011 J. Am. Ceram. Soc. 94 3600.
[21]	Korthuis V, Khosrovani N, Sleight A W 1995 J. Series Chem. Mater. 7 412
[22]	Yuan H L, Yuan B H, Li F, Liang E J 2012 Acta Phys. Sin. 61 226502 (in Chinese)[袁焕丽, 袁保合, 李芳, 梁二军2012物理学报61 226502]
[23]	Sahoo P P, Sumithra S, Madras G, Row T N G 2011 Inorg. Chem. 50 8774
[24]	Liu Q Q, Yang J, Sun X J, Cheng X N, Tang H, Li H H 2014 Appl. Surf. Sci. 313 41
[25]	Hisashige T, Yamaguchi T, Tsuji T, Yamamura Y 2006 J. Ceram. Soc. Jpn. 114 607
[26]	Yanase I, Kojima T, Kobayashi H 2011 Solid State Commun. 151 595
[27]	Yuan B H, Yuan H L, Song W B, Liu X S, Cheng Y G, Chao M J, Liang E J 2014 Chin. Phys. Lett. 31 076501
[28]	Yuan B H, Liu X S, Song W B, Cheng Y G, Liang E J, Chao M J 2014 Phys. Lett. A 378 3397
[29]	Yuan B H, Liu X S, Mao Y C, Wang J Q, Guo J, Cheng Y G, Liang E J, Chao M J 2015 Mater. Chem. Phys. 170 162
[30]	Petruska E A, Muthu D V S, Carlson S, Krogh Andersen A M, Ouyang L, Kyuger M B 2010 Solid State Commun. 150 235

施引文献

[1]	Chen J, Wang F F, Huang Q Z, Hu L, Song X P, Deng J X, Yu R B, Xing X R 2013 Sci. Rep. 3 2458
[2]	Yan J, Sun Y, Wen Y C, Chu L H, Wu M M, Huang Q Z, Wang C, Lynn J W, Chen Y L 2014 Inorg. Chem. 53 2317
[3]	Yao W J, Jiang X X, Huang R J, Li W, Huang C J, Lin Z S, Li L F, Chen C T 2014 Chem. Commun. 50 13499
[4]	Closmann C, Sleight A W, Hargarth J C 1998 J. Solid State Chem. 139 424
[5]	Bridges F, Keiber T, Juhas P, Billinge S J L, Sutton L, Wilde J, Kowach G R 2014 Phys. Rev. Lett. 112 045505
[6]	Liu Q Q, Yu Z Q, Chen G F, Yao J L, Sun X J, Cheng X N, Yang J 2014 Ceram. Int. 40 8195
[7]	Liu X S, Cheng F X, Wang J Q, Song W B, Yuan B H, Liang E J 2013 J. Alloys Compd. 553 1
[8]	Khosrovani N, Sleight A W 1997 J. Solid State Chem. 132 355
[9]	Khosrovani N, Korthuis V, Sleight A W 1996 Inorg. Chem. 35 485
[10]	Withers R L, Evans J S O, Hanson J, Sleight A W 1998 J. Solid State Chem. 137 161
[11]	Withers R L, Tabira Y, Evans J S O, King I J, Sleight A W 2001 J. Solid State Chem. 157 186
[12]	Carlson S, Andersen A M K 2001 J. Appl. Crystallogr. 34 7
[13]	Hemamala U L C, El-Ghussein F, Muthu D V S, Andersen A M K, Carlson S, Ouyang L, Kruger M B 2007 Solid State Commun. 141 680
[14]	Ge X H, Mao Y C, Li L, Li L P, Yuan N, Cheng Y G, Guo J, Chao M J, Liang E J 2016 Chin. Phys. Lett. 33 046503
[15]	Song W B, Wang J Q, Li Z Y, Liu X S, Yuan B H, Liang E J 2014 Chin. Phys. B 23 066501
[16]	Li Q J, Yuan B H, Song W B, Liang E J, Yuan B 2012 Chin. Phys. B 21 046501
[17]	Chu L H, Wang C, Sun Y, Li M C, Wan Z P, Wang Y, Dou S Y, Chu Y 2015 Chin. Phys. Lett. 32 047501
[18]	Guo X G, Lin J C, Tong P, Wang M, WU Y, Yang C, Song B, Liu S, Sun Y P 2015 Appl. Phys. Lett. 107 202406
[19]	Wang F F, Xie Y, Chen J, Fu H G, Xing X R 2013 Appl. Phys. Lett. 103 221901
[20]	Hu P H, Chen J, Sun C, Deng J X, Xing X R, Snyder R L 2011 J. Am. Ceram. Soc. 94 3600.
[21]	Korthuis V, Khosrovani N, Sleight A W 1995 J. Series Chem. Mater. 7 412
[22]	Yuan H L, Yuan B H, Li F, Liang E J 2012 Acta Phys. Sin. 61 226502 (in Chinese)[袁焕丽, 袁保合, 李芳, 梁二军2012物理学报61 226502]
[23]	Sahoo P P, Sumithra S, Madras G, Row T N G 2011 Inorg. Chem. 50 8774
[24]	Liu Q Q, Yang J, Sun X J, Cheng X N, Tang H, Li H H 2014 Appl. Surf. Sci. 313 41
[25]	Hisashige T, Yamaguchi T, Tsuji T, Yamamura Y 2006 J. Ceram. Soc. Jpn. 114 607
[26]	Yanase I, Kojima T, Kobayashi H 2011 Solid State Commun. 151 595
[27]	Yuan B H, Yuan H L, Song W B, Liu X S, Cheng Y G, Chao M J, Liang E J 2014 Chin. Phys. Lett. 31 076501
[28]	Yuan B H, Liu X S, Song W B, Cheng Y G, Liang E J, Chao M J 2014 Phys. Lett. A 378 3397
[29]	Yuan B H, Liu X S, Mao Y C, Wang J Q, Guo J, Cheng Y G, Liang E J, Chao M J 2015 Mater. Chem. Phys. 170 162
[30]	Petruska E A, Muthu D V S, Carlson S, Krogh Andersen A M, Ouyang L, Kyuger M B 2010 Solid State Commun. 150 235

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