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中国物理学会期刊

SnSe2的忆阻及磁阻效应

CSTR: 32037.14.aps.69.20200160

Memristive and magnetoresistance effects of SnSe2

CSTR: 32037.14.aps.69.20200160
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  • 忆阻和磁阻效应在当前电子信息存储领域都有着广泛的应用. 近年来, 硫族化合物SnSe2作为一种同时具有忆阻与磁阻效应的存储材料, 受到广大科研工作者的关注, 该材料的电输运机理的深入探索具有十分重要意义. 本文采用熔融法结合放电等离子烧结技术成功制备了高纯度的SnSe2块体材料, 测量了不同温度、不同磁场条件下的电流-电压特性曲线, 系统地研究了其忆阻与磁阻效应. 研究表明: 不同温度下的忆阻特征可被归结为缺陷控制下的空间电荷限制电流效应; 温度降低导致忆阻现象减弱, 这与低温下杂质电离较弱导致可接受注入载流子的缺陷变少从而空间电荷限制电流效应变弱有关. 同时发现, 样品在低温下呈现较大的负磁阻效应, 这是因为在低温下杂质散射占主导作用, 电子在传导时会受到杂质的多重散射导致载流子局域化, 负磁阻效应与磁场对载流子局域化的抑制作用有关; 随着温度升高, 散射机制逐渐由杂质散射转变为晶格散射为主, 负磁阻效应逐渐转变为正磁阻效应.

     

    Memristor and magnetoresistance (MR) are widely used in the field of information storage. In recent years, SnSe2, as an information storage material with both memristor and MR effects, has received a lot of attention of the researchers. It is of great significance to further explore its electrical transport mechanism. In this paper, the high-purity bulk SnSe2 samples are prepared by melting method together with spark plasma sintering. The V-I curves are measured under different temperatures and magnetic fields. The memristive and MR effect of SnSe2 are systematically investigated. After the memristive characteristics are excluded from interfacial junction effect, phase transition and conductive wire channels, the memristive effect at different temperatures is attributed to the space charge limiting current effect under defect control. Under low electric field conditions, the internal carrier concentration of material is much higher than the injected carrier concentration and the V-I curve obeys ohmic conduction. When the voltage increases to the switching voltage Von, the internal defects of the material are filled with the injected carriers as the transport time of the injected carrier is less than the dielectric relaxation time, and the V-I curves deviate from ohmic conductivity. When the voltage reaches the transition voltage VTFL, the injected carrier increases exponentially, and the V-I curve presents negative differential phenomenon. Finally, the space charge inside the material will limit the further injection of external carriers, and the V-I curve follows the Child law. As the temperature decreases to 10 K, the memristive phenomenon weakens because a large number of defects for accepting the injected carriers are reduced due to the decrease of impurity ionization at low temperatures. At the same time, the sample exhibits a large negative MR at 10 K and 100 K. When impurity scattering predominates, the electrons will be subjected to multiple scattering by the impurities, resulting in localization of carriers. The negative MR effect is related to the inhibition of the carrier localization by the magnetic field. In our work, a large negative MR of about –37% at 0.6 T and 10 K are obtained, which is likely to originate from the disordered distribution of Se vacancy in the material. With the increase of temperature, the scattering mechanism gradually evolves from the impurity scattering into the lattice scattering, and the negative MR effect gradually develops into the positive MR effect.

     

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