搜索

x
中国物理学会期刊

三维多孔陶瓷骨架增强的复合电解质

CSTR: 32037.14.aps.69.20201552

Three-dimensional porous ceramic framework reinforcing composite electrolyte

CSTR: 32037.14.aps.69.20201552
PDF
HTML
导出引用
  • 全固态锂电池在安全性和能量密度上都表现出极大的优势, 因而在储能领域备受关注. 有机-无机复合电解质结合了刚性无机陶瓷电解质优异的室温离子电导率和柔性有机聚合物电解质良好的可弯曲性, 被认为是全固态锂电池最理想的电解质材料之一. 然而, 传统制备方法所使用的零维或一维无机填料具有团聚趋向且填料之间被聚合物相隔离, 无法形成快速而连续的锂离子传输通道, 旨在通过增加无机填料含量来提升复合电解质综合性能的方法难见成效. 三维多孔陶瓷骨架因具有连续的锂离子快速传导网络, 且其自支撑结构能够防止无机颗粒的团聚, 近年来作为无机填料被越来越广泛地应用于复合电解质中. 针对此, 本文首先详细阐释了三维多孔陶瓷骨架对复合电解质电导率提升的机理, 综述了近年来的相关研究结果, 证实了三维多孔陶瓷骨架对复合电解质电导率和热稳定性的有利作用, 然后对三维多孔陶瓷骨架不同的制备方法进行总结, 为寻找更优的合成方法提供基础, 最后探讨三维多孔陶瓷骨架的优化方向, 在已有研究的基础上提出可行的改善策略.

     

    All solid-state lithium batteries demonstrate excellent characteristics of high safety and energy density, which make them very promising energy storage devices. Among various kinds of solid electrolytes, rigid-flexible coupling composite electrolyte combines the advantages of rigid solid inorganic ceramic electrolytes, i.e., excellent room temperature ionic conductivity, and of flexible solid polymer electrolytes, i.e., the flexibility, and thereby is considered to be one of the most ideal electrolyte candidates for all solid-state lithium batteries. Dispersing 0- or 1-dimensional inorganic fillers is a widespread method to fabricate rigid-flexible coupling composite, where the ionic conductivity of polymer can be improved by one order of magnitude mainly due to the decreased degree of crystallinity. However, aim to further increase the ionic conductivity by increasing the filler content cannot be accomplished because of the fillers' tendency to aggregation. what's more, the highly conductive inorganic fillers are separated by the polymer phase and thus cannot form fast and continuous Li+ transportation channels. Accordingly, inorganic fillers which can provide percolated pathway for Li+ transportation and avoid aggregating are highly desirable. To this end, different from adding 0- or 1-dimensional inorganic fillers into polymer matrices, polymers can be cast into porous inorganic substrates, that is, 3-dimensional porous ceramic framework, to obtain organic-inorganic composite electrolyte, in which organic phase, inorganic phase, and organic/inorganic interfacial phase are all continuous for fast Li+ transportation. And meanwhile, its self-supported structure prevents the agglomeration of inorganic particles. In recent years, the 3-dimensional porous ceramic framework has been more and more frequently used in rigid-flexible coupling composite electrolytes. To have a deep insight into the positive function of 3-dimensional porous ceramic framework, in this review, we firstly reveal the mechanism of the huge improvement in the ionic conductivity and thermostability of the composite electrolyte. Then, we summarize the frequently used preparation methods of the 3-dimensional porous ceramic framework reported recently. Finally, for the future perspective of rigid-flexible coupling composite electrolyte development, we propose two feasible improvement strategies. This review can thereby provide great significance of designing solid electrolytes with comprehensive performance for all solid-state lithium batteries with high energy density and superior safety.

     

    目录

    /

    返回文章
    返回