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中国物理学会期刊

基于层状WS2调制激光泵浦的光学参量振荡中红外运转特性研究

Operation characteristics of Mid-infrared optical parametric oscillation pumped by layered WS2 modulated laser

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  • 光学参量振荡器是重要的中红外相干光源。具有非线性吸收特性的二维过渡金属硫化物,有望成为光学参量振荡器基频激光的优良调制元件。目前,国际上对二维过渡金属硫化物调制激光器的研究,主要集中在实验工作上,结合动力学理论的研究较少。在这项工作中,首先实验测量了层状二硫化钨(WS2)调制固体激光的输出特性;其次,结合主动声光Q开关,实现主被动双调Q 光参量振荡的运转,得到了纳秒脉冲宽度的中红外脉冲,并研究了WS2对光参量转换的优化特性,发现WS2纳米片除了能够压缩脉冲、提高峰值功率外,还能缓解单主动调Q 光学参量振荡器中的“输出饱和下降”现象;最后,基于WS2的非线性透过率曲线,考虑非均匀展宽机制和大信号下的非饱和吸收,计算了可饱和吸收的基态和激发态吸收截面、激发态能级寿命、初始基态粒子数密度等参数,并首次求解了层状WS2调制光学参量振荡器的速率方程组,动力学理论计算值与实验值相符。论文在实验上展示了二维过渡金属硫化物对激光非线性频率变换的优化效果,尤其是对热效应的缓解;同时,在理论上给出了一种计算二维材料可饱和吸收特性参数的方法,为二维材料调制激光的动力学模拟提供参数依据。

     

    Optical parametric oscillator (OPO) is an important mid-infrared coherent light source. Two dimensional (2D) transition metal dichalcogenide (TMDC) with nonlinear absorption of near-infrared-wavelength light is expected to be a prospective modulating switch for OPO’s fundamental laser. At present, the international research on 2D-TMDC-modulated laser is mainly focused on the experimental method, but less on the dynamic theory. In this work, firstly, the characteristics of a homemade 3.5nm-thickness tungsten disulfide (WS2) sample are measured and analyzed. The nonlinear transmission is figured and fitted, which implies the performance of WS2’s saturable absorption. Then, the output characteristics of WS2 saturable absorber (SA) modulated solid-state laser are measured experimentally. Although the photon energy of 1.06 ?m-wavelength laser is less than the bandgap energy of 3.5nm WS2, the sample still exhibits saturable absorption. This may be attributed to the mechanisms of defect-induced absorption, coexistence of states, edge-state of material, and two-photon absorption, etc. Secondly, combined with active acousto-optic (AO) modulator, the active and passive Q-switched OPO with idler-light oscillation is implemented, and the nanometer pulse-width mid-infrared pulse is obtained. The implementation of AO modulator is to manage the regular switching time to reduce the pulse peak-to-peak vibration of fundamental light and improve the peak power. The optimization characteristics of WS2 for OPO are studied. Based on the saturable absorption characteristics, the output pulse is compressed by 60%, the peak power is improved by 191%, and the stability of pulse train is improved by 79.62%. Especially, the insertion of WS2 nanosheet could alleviate the "output saturation and drop" phenomenon in singly active-Q-switched OPO. In the end, based on the nonlinear transmittance curve measured for WS2, the absorption cross sections of ground and excited states (1.732×10-17 cm2 and 4.758×10-19 cm2), the lifetime of excited-state energy level (400.6 μs), and the initial population density of ground state (1.741×1022 cm-3) are calculated considering the inhomogeneous-broadening mechanism and non-saturable absorption. The calculated values for the WS2 sample corresponds to the typical value of TMDC SA. The rate equations of OPO modulated by WS2 SA are numerically solved by use of the parameters derived above. The calculated values are in good agreement with the experimental ones. In a conclusion, this work contributes both experimentally and theoretically. In experiment, the optimization effect of 2D TMDC on nonlinear optical conversion is observed, especial the alleviation to thermal effect. In theory, a method to estimate the saturable absorption characteristic parameters of 2D materials is given. It provides reference for the dynamic simulation of 2D materials modulated laser. This work not only experimentally demonstrates the optimization effect of 2D TMDC on nonlinear optical conversion, but also theoretically gives a method to estimate the saturable absorption characteristic parameters of 2D materials. It provides reference for the dynamic simulation of 2D materials modulated laser.

     

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