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中国物理学会期刊

TaC微粒对Ti-6Al-4V合金微弧氧化层结构和性能的影响

CSTR: 32037.14.aps.71.20210835

Effects of TaC microparticles on structure and properties of micro-arc oxidation coating on Ti-6Al-4V alloy

CSTR: 32037.14.aps.71.20210835
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  • 为了提高钛合金表面微弧氧化层在海洋环境中的抗腐蚀和耐磨损性能, 在硅酸盐系电解液中添加不同浓度粒径在1 μm左右的TaC微粒, 制备了TaC掺杂微弧氧化层. 通过扫描电子显微镜、能谱仪和X射线光电子能谱仪等对微弧氧化层的形貌、元素组成及其化学状态进行表征与分析, 并对比评价了钛合金表面TaC掺杂微弧氧化层的厚度、表面粗糙度、硬度、耐磨性以及耐蚀性. 结果表明: 通过向电解液中添加TaC微粒, 钛合金表面微弧氧化层中存在TaC和Ta2O5; 较未添加TaC微粒制备微弧氧化层, 其表面形貌更为致密, 硬度提高了约83.2%, 在模拟海水中的摩擦系数由0.2降到了0.148, 由磨粒磨损转变为粘着磨损, 腐蚀电流密度下降了2个数量级, 并通过构建微弧氧化层在模拟海水中的磨损和腐蚀失效模型, 揭示了微弧氧化层中掺入TaC微粒对改善其抗腐耐磨性能的内在机理.

     

    In order to improve the corrosion resistance and wear properties of the micro arc oxidatin (MAO) coatings on Ti-6Al-4V alloy in the marine environment, TaC-doped MAO coatings are prepared by adding different concentrations of TaC microparticles with a particle size of about 1 μm into the silicate-based electrolyte. The morphology, elemental distribution and composition of the coatings are characterized and analyzed by SEM, EDS and XPS. The thickness, roughness, hardness, wear resistance and corrosion resistance for each of the three MAO coatings are evaluated and their corresponding values of these coatings are compared with each other. The results show that by adding TaC microparticles into the base electrolyte, TaC and Ta2O5 are present in the MAO coatings on titanium alloy. Compared with the MAO coating without TaC, the surface morphology of the coating with TaC is dense and the hardness is increased by about 83.2%. The friction coefficient of the coating in the simulated seawater decreases from 0.2 to 0.148, changing from serious abrasive wear to slight adhesive wear. The corrosion current density of this coating decreases by two orders of magnitude. Furthermore, by constructing the wear and corrosion failure model of the MAO coatings in the simulated seawater, the internal mechanism of doping TaC microparticles into the MAO coating to improve its corrosion resistance and wear resistance is revealed.

     

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