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中国物理学会期刊

晶界添加PrCu合金对(Pr, Nd, Dy)32.2Co13Cu0.4FebalB0.98M1.05磁体磁性能与微观组织的影响

CSTR: 32037.14.aps.71.20220406

Effect of Pr80Cu20 grain boundary addition on microstructure and magnetic properties of (Pr, Nd, Dy)32.2Co13Cu0.4FebalB0.98M1.05 magnet

CSTR: 32037.14.aps.71.20220406
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  • 通过在(Pr, Nd, Dy)32.2Co13Cu0.4FebalB0.98M1.05(M = Al, Ga, Zr)磁体中添加低熔点合金Pr80Cu20, 提高磁体中的Cu含量, 从而调控Co在富稀土相中的分布. 相较于原磁体, 掺PrCu磁体的剩磁保持不变, 矫顽力提升约1.3 kOe, 居里温度、剩磁温度系数和不可逆磁损均有所改善. 通过微观组织观察发现, 原磁体二级回火态晶界处同时存在贫Co相与富Co相, 但掺PrCu磁体二级回火态中, Cu和Co在晶界相中的分布均匀性明显改善, 从而有效地消除了富Co相. 由于软磁性相R2(Fe, Co)17 (R = Pr, Nd, Dy) 容易与富Co相共生, 有害于永磁性能, 富Co相的消除可能是掺PrCu磁体二级回火态矫顽力提升的重要原因.

     

    With the aim of increasing Cu concentration to regulate the distribution of Co elements in RE-rich phase, the low-melting-point Pr80Cu20 intergranular alloy is introduced into the (Pr, Nd, Dy)32.2Co13Cu0.4FebalB0.98M1.05 (M = Al, Ga, Zr) magnet. Comparing with the original magnet, the remanence of PrCu-doped magnet is basically unchanged, and the coercivity is increased by approximately 1.3 kOe. Simultaneously, the Curie temperature, remanence temperature coefficient and irreversible flux loss are slightly improved. Microstructural study reveals that the Co-lean phase and the Co-rich phase coexist in the grain boundary in the 2nd-annealed original magnet. However, for the PrCu-doped magnet, the uniform distribution of Cu and Co elements in the intergranular phase are evidently improved, resulting in the elimination of the Co-rich phase. Since the R2(Fe, Co)17 (R = Pr, Nd, Dy) soft magnetic phase easily coexist with the Co-rich phase and are detrimental to the coercivity, the elimination of Co-rich intergranular phase may be an important reason for the higher coercivity of the 2nd-annealed PrCu-doped magnet than that of the original magnet.

     

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