搜索

x
中国物理学会期刊

基于法布里-珀罗干涉仪测量大气环境CO2的方法

CSTR: 32037.14.aps.73.20231224

Method of measuring atmospheric CO2 based on Fabry-Perot interferometer

CSTR: 32037.14.aps.73.20231224
PDF
HTML
导出引用
  • CO2是主要的温室气体之一, 它的排放和累积导致温室效应加强, 进而引起全球气候变化, 因此获取大气环境中CO2的浓度变化对研究气候变化意义重大. 针对低成本、快速和在线精确测量大气环境CO2的技术需求, 本文构建了基于法布里-珀罗干涉仪的CO2大气浓度在线测量系统, 并研究了精确获取其浓度反演方法. 采用基于微机电系统(MEMS)技术的热辐射源作为法布里-珀罗干涉仪系统光源, 设计透射式光路代替常见的折射式光路. 通过静电控制两镜片的间距, 改变干涉谱, 实现10 nm步长的中心波长的干涉峰调节, 扫描获得CO2实时在线吸收光谱, 基于差分吸收光谱原理获取了CO2气体的浓度. 利用样气标定系统, 并用商用光声光谱多气体分析仪校验系统, 结果表明, 该系统检测限达1.09 ×10–6, 检测精度为±1.13×10–6, 测量误差小于1%. 在煤城淮北开展了大气环境CO2实时在线检测, 并与商用光声光谱分析仪开展比对观测实验, 二者相关系数R = 0.92. 实验结果表明, 研发的法布里-珀罗干涉仪系统能够满足大气环境CO2浓度的快速、在线高精度测量技术需求.

     

    CO2 is one of the main greenhouse gases. Its emission and accumulation lead to the strengthening of the greenhouse effect, which in turn causes global climate change. Therefore, it is of great significance to obtain the change of CO2 concentration in the atmospheric environment for the study of climate change. In order to meet the requirements of low cost, fast, on-line and accurate measurement of CO2 in atmospheric environment, a CO2 gas concentration measurement system based on Fabry-Perot interferometer is built in this work. The thermal radiation source based on micro-electro-mechanical system (MEMS) technology is used as a light source of the Fabry-Perot interferometer system, and the transmission optical path is designed to replace the common refractive optical path. By electrostatically controlling the distance between the two lenses and changing the interference spectrum, the interference peak adjustment of the center wavelength of the 10 nm step is realized, and the absorption spectrum is obtained by scanning. Based on the principle of differential optical absorption spectroscopy, the concentration of CO2 gas is obtained, and the real-time on-line monitoring of CO2 concentration is realized. Using the sample gas calibration system and the commercial photoacoustic spectroscopy multi-gas analyzer to verify the system, the results show that the detection limit of the system is 1.09×10–6, the detection accuracy is ±1.13×10–6, and the measurement error is less than 1%. Real-time online monitoring of atmospheric CO2 has been conducted in Huaibei, a coal city. A comparative observational experiment is performed between this system and a commercial photoacoustic spectroscopy multi-gas analyzer. The two systems show consistent trends in measuring CO2 variations, with a correlation coefficient of R=0.92. It shows that the Fabry-Perot interferometer system can meet the requirement of rapid, convenient and high precision measurement of CO2 concentration in the environment.

     

    目录

    /

    返回文章
    返回