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中国物理学会期刊

钙钛矿基三结叠层太阳电池的研究进展

CSTR: 32037.14.aps.73.20241187

Research progress of perovskite-based triple-junction tandem solar cells

CSTR: 32037.14.aps.73.20241187
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  • 单结太阳电池的能量转换效率受限于Shockley-Queisser理论极限, 而突破该极限的最有效策略是构建多结叠层太阳电池. 多结叠层太阳电池通过堆叠多个子电池, 可针对太阳光谱的特定部分进行优化. 钙钛矿材料具有连续可调的能带结构, 为多结叠层电池中的吸光材料组合提供了新的选项. 在钙钛矿基叠层太阳电池领域, 三结叠层太阳电池已经取得了一定进展, 在光伏产业中展现出巨大潜力. 本文首先重点介绍了三结叠层太阳能器件结构及面临的科学问题, 然后介绍了钙钛矿基三结叠层电池的研究进展, 包括钙钛矿/钙钛矿/硅叠层电池、钙钛矿/钙钛矿/有机叠层电池和全钙钛矿叠层电池. 最后, 本文分析了进一步提升三结叠层太阳电池性能的研究方向, 为制备高效三结电池提供了指导.

     

    The energy conversion efficiency of single-junction solar cells is limited by the Shockley-Queisser theory and the most effective strategy to break through this limit is to fabricate multi-junction tandem solar cells. Perovskite materials provide a continuously tunable energy band structure, offering a new option for light-absorbing materials in multi-junction tandem cells. In the field of perovskite-based multi-junction tandem solar cells, triple-junction tandem solar cells have demonstrated great potential. The present paper introduces the configuration of triple-junction solar cells and its facing three scientific challenges. 1) Ensuring energy level alignment among sub-cells is a critical concern for three-junction batteries. Specifically, the top wide-band gap sub-cell must possess a band gap ranging from 1.8 to 2.2 eV; however, current perovskite material systems with wide-band gaps exhibit certain defects. 2) It is essential to achieve current matching in multi-junction tandem solar cells while optimizing the absorption layer and minimizing parasitic absorption in order to maximize the current output of solar cells. 3) The functional layers of multi-junction tandem solar cells are stacked sequentially using different deposition methods, which imposes higher compatibility requirements on the intermediate interconnect layers. Subsequently, the research progress of perovskite-based triple-junction tandem solar cells is introduced, including perovskite/perovskite/silicon tandem solar cells, perovskite/perovskite/organic tandem solar cells, and all-perovskite tandem solar cells. Their respective highest efficiencies are 19.4%, 23.87%, and 27.1%. Finally, this paper explores the research directions for further improving the performance of triple-junction solar cells. In addition to improving energy conversion efficiency, perovskite-based solar cells must also solve the stability problems in order to achieve future commercialization, and provide guidance for the development of efficient triple-junction cells.

     

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