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中国物理学会期刊

基于埋底界面修饰策略制备正式钙钛矿太阳电池

CSTR: 32037.14.aps.74.20241549

Fabrication of n-i-p perovskite solar cells based on strategy of buried interface modification

CSTR: 32037.14.aps.74.20241549
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  • 二氧化锡是正式钙钛矿太阳电池理想的电子传输层材料. 二氧化锡与钙钛矿之间的界面缺陷是制约钙钛矿太阳电池转换效率提高的关键因素. 因此, 本文提出了一种基于埋底界面修饰策略制备正式钙钛矿太阳电池的方法. 通过在二氧化锡中掺杂甲基溴化胺, 形成埋底界面, 减少了二氧化锡与钙钛矿之间的界面缺陷, 提升了二氧化锡的电子迁移率, 并促进高质量钙钛矿材料的生长, 制备的正式钙钛矿太阳电池转换效率达23.12%, 为制备高效正式钙钛矿太阳能电池提供了一种有效策略.

     

    Normal (n-i-p) perovskite solar cells (PSCs) have received increasing attention due to their advantages such as high conversion efficiency and good stability. Tin dioxide is an ideal electron transport layer material for normal perovskite solar cells. Among various available electron transport layers, tin dioxide stands out because of its excellent stability, low density of defect states, and appropriate energy levels. The interface defects between tin dioxide and perovskite are the key factors restricting the improvement of the conversion efficiency in perovskite solar cells. Therefore, a method of fabricating normal perovskite solar cells based on the buried interface modification strategy is proposed in this work. By doping methylammonium bromide into tin dioxide to form a buried interface, the interface defects between tin dioxide and perovskite are reduced, the electron mobility of tin dioxide is enhanced, and the growth of high-quality perovskite materials is promoted. The conversion efficiency of the normal perovskite solar cells reaches 23.12%, providing an effective strategy for fabricating high-efficiency normal perovskite solar cells.

     

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