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中国物理学会期刊

p型Bi2Te3基材料的垂直转角挤压制备与热电性能

CSTR: 32037.14.aps.74.20250152

Preparation of vertical corner extrusion and thermoelectric properties of p-type Bi2Te3 based materials

CSTR: 32037.14.aps.74.20250152
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  • 粉末冶金制备技术是制备兼具优异力学性能和热电性能Bi2Te3基块状材料的重要途径, 但是粉末冶金制备过程中样品取向损失导致材料热电性能不高, 开发具有强板织构、细晶粒Bi2Te3基热电材料的制备技术是高性能Bi2Te3基热电材料研究的重点. 本文采用垂直转角挤压制备技术制备了系列p型Bi2Te3基材料, 系统研究了挤压温度对材料微结构和织构特征的影响规律及其对材料热电性能的影响规律, 在垂直转角挤压过程中, 材料经历了剧烈的塑性变形, 导致材料内部晶粒的破碎、重排及偏转, 同时挤压过程中高温有助于材料中晶粒的动态再结晶和生长过程, 实现了晶粒的细化, 773 K挤压样品在垂直于压力方向和平行于压力方向上分别取得了F(00l)=0.51和F(110)=0.30的高取向因子, 即从热压样品中面织构向挤压样品中板织构的转变, 这种微结构特征显著地提升了样品的载流子迁移率, 773 K挤压样品室温下载流子迁移率高达345.4 cm2·V–1·s–1, 与区熔样品相当, 表现出优异的电输运性能, 室温下功率因子达到4.43 mW·m–1·K–2, 与此同时, 773 K挤压样品的晶格热导率和双极热导率之和在323 K时降低至最小值0.78 W·m–1·K–1, 最终773 K挤压样品在323 K时获得最大ZT值1.13, 较热压样品提高了近70%. 该研究为高性能强板织构、细晶粒Bi2Te3基热电材料的制备提供了新途径, 为微型热电器件的制造奠定了重要基础.

     

    The preparation technology of powder metallurgy is an important way to prepare Bi2Te3-based bulk materials with excellent mechanical properties and thermoelectric properties. However, the loss of sample orientation during the preparation of powder metallurgy results in low thermoelectric properties of the materials. The development of high-performance Bi2Te3-based thermoelectric materials with strong plate texture and fine grains is the focus of research on high-performance Bi2Te3-based thermoelectric materials. In this paper, a series of p-type Bi2Te3-based materials is prepared by vertical corner extrusion preparation technology. The influences of extrusion temperature on the microstructure and texture characteristics of the material and its influence on the thermoelectric properties of the material are systematically studied. In the vertical corner extrusion process, grains preferentially grow along the minimum resistance direction perpendicular to the pressure, that is, along the extrusion direction, thereby further enhancing the (00l) texture of the original hot-pressed sample; in the direction parallel to the pressure, due to friction with the inner wall of the die in the extrusion process, this frictional resistance will promote the inversion of the grains, so that the grains are arranged in a directional manner to reduce the frictional resistance, thus forming the (110) texture, which is not present in the original hot-pressed sample, in the extruded sample, and finally completing the transition from the hot-pressed sample to the plate texture of the extruded sample. When the extrusion temperature is low, the atomic diffusion rate is low, which limits the dynamic recrystallization of the grain, the grain growth process, and the grain deflection speed. With the increase of the extrusion temperature, these processes can be carried out rapidly, thus forming a more obvious plate texture characteristic. The 773 K extruded sample achieves high orientation factors of F(00l) = 0.51 and F(110) = 0.30 in the directions perpendicular to the pressure and parallel to the pressure, respectively, and the carrier mobility is as high as 345.4 cm2·V–1·s–1 at room temperature, which is comparable to the carrier mobility of the zone melt sample, showing excellent electrical transport performance. The power factor reaches 4.43 mW·m–1·K–2 at room temperature. At the same time, the sum of lattice thermal conductivity and bipolar thermal conductivity of the 773 K extruded sample decreases to a minimum value of 0.78 W·m–1·K–1 at 323 K. Finally, the 773 K extruded sample obtains a maximum ZT value of 1.13 at 323 K, which is nearly 70% higher than that of the hot-pressed sample. This research provides a new way for preparing high-performance strong plate textures and fine-grained Bi2Te3-based thermoelectric materials, and lays an important foundation for fabricating micro thermoelectric devices.

     

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