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中国物理学会期刊

基于水窗高次谐波阿秒光源的瞬态吸收光谱装置

CSTR: 32037.14.aps.74.20250550

Apparatus for transient absorption spectroscopy based on water-window high-order harmonic attosecond light sources

CSTR: 32037.14.aps.74.20250550
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  • 以软X射线相干光源作为超快探针的瞬态吸收光谱技术在化学、生物、材料领域有着广泛的应用前景. 本文介绍一种基于桌面式软X射线光源的瞬态吸收装置的设计, 该装置利用短波红外激光来驱动软X射线高次谐波阿秒光源的产生, 最大光子能量进入水窗波段(>300 eV). 产生的阿秒光源与近红外激光通过孔镜合束实现了泵浦探测光路的时空同步, 1 h内时间稳定性优于10 fs. 利用该装置开展了氩L边及碳K边瞬态吸收光谱的初步研究, 为实现元素分辨、时间分辨、跃迁通道分辨的电子动力学测量提供了重要的工具.

     

    Transient absorption spectroscopy using soft X-ray coherent light sources as ultrafast probes holds significant potential applications in chemistry, biology, and materials science. This article presents the design of a transient absorption apparatus based on desktop soft X-ray light sources. A commercial femtosecond laser system (4.4 mJ, 25 fs, 800 nm, 1 kHz) drives an optical parametric amplifier, generating a 900 μJ, 28 fs, 1440 nm short-wavelength infrared (SWIR) pulse. This SWIR pulse is spectrally broadened and temporally compressed into a few-cycle pulse (400 μJ, 16.5 fs, 1530 nm) by a hollow-core fiber compressor. Then, few-cycle SWIR pulse drives the generation of attosecond soft X-ray high-order harmonic radiation, with the maximum photon energy extending into the water window region (>300 eV). The spectral resolution of the soft X-ray spectrometer is determined to be 334 meV at 243 eV. The remaining 800 nm pump pulse from the OPA system is combined with the high-order harmonic soft X-ray probe by using a hole mirror, forming a Mach-Zehnder interferometer with a time jitter of less than 10 fs during the one-hour data acquisition. This setup demonstrates the feasibility of performing time-resolved soft X-ray spectroscopy in a compact experimental configuration. Preliminary studies of transient absorption near the argon L-edge and carbon K-edge are conducted, demonstrating that this system can be used as a powerful tool for element-specific, time-resolved, and transition-channel-resolved investigations of electron dynamics.

     

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